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| CAS No.: | 24602-86-6 |
|---|---|
| Name: | Tridemorph |
| Article Data: | 36 |
| Molecular Structure: | |
|
|
|
| Formula: | C19H39NO |
| Molecular Weight: | 297.525 |
| Synonyms: | 2,6-Dimethyl-4-tridecylmorpholine;N-Tridecyl-2,6-dimethylmorpholine;NSC 232676; |
| EINECS: | 246-347-3 |
| Density: | 0.856 g/cm3 |
| Melting Point: | <25 °C |
| Boiling Point: | 371.268 °C at 760 mmHg |
| Flash Point: | 109.499 °C |
| Hazard Symbols: |
 T,  N
|
| Risk Codes: | 20/22-38-50/53-61 |
| Safety: | 45-53-60-61 |
| Transport Information: | UN 3082 |
| PSA: | 12.47000 |
| LogP: | 5.34450 |
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Chemistry
Molecular Formula: C19H39NO 
Formula Weight: 297.52
IUPAC Name: 2,6-dimethyl-4-tridecylmorpholine
Synonyms: n-tridecyl-2,6-dimethylmorpholine ; Tridecyl-2,6-dimethylmorpholine ; 2,6-dimethyl-n-tridecyl-morpholin ; Tridemorph
Flash Point: 109.5 °C
Boiling Point: 371.3 °C at 760 mmHg
Density: 0.855 g/cm3
pH of 2,6-dimethyl-4-tridecylmorpholin (24602-86-6): 7-8
Vapour Pressure: 1.04E-05 mmHg at 25°C
Storage temp.: 0-6°C
Index of Refraction: 1.449
Solubility in water: 2,6-dimethyl-4-tridecylmorpholin (24602-86-6) is insoluble (soluble in most organic solvents)
Appearence: 2,6-dimethyl-4-tridecylmorpholin (24602-86-6) is a yellow oily liquid
Uses
2,6-dimethyl-4-tridecylmorpholin (24602-86-6) is used as a pharmaceutical intermediate and morpholine fungicide. It is also used for the prevention and control barley and wheat powdery mildew, wheat leaf rust, stripe rust, cucumbers, potatoes, rubber and pea powdery mildew.
Production
In the presence of sulfuric acid, 2,6-dimethyl-4-tridecylmorpholin (24602-86-6) is obtained from N, N-di (β-hydroxypropyl) amine 13 by dehydration cyclization at 160 °C.
Toxicity Data With Reference
| 1. | orl-rat LD50:650 mg/kg | GUCHAZ Guide to the Chemicals Used in Crop Protection 6 (1973),522. | ||
| 2. | orl-mus LD50:1560 mg/kg | VPITAR Voprosy Pitaniya. Problems of Nutrition. 39 (6)(1981),55. | ||
| 3. | orl-cat LD50:540 mg/kg | VPITAR Voprosy Pitaniya. Problems of Nutrition. 39 (6)(1981),55. | ||
| 4. | orl-rbt LD50:750 mg/kg | 28ZEAL Pesticide Index. 5 (1976),229. | ||
| 5. | orl-gpg LD50:1 g/kg | VPITAR Voprosy Pitaniya. Problems of Nutrition. 39 (6)(1981),55. |
Safety Profile
Moderately toxic by ingestion. Experimental teratogenic effects. When heated to decomposition it emits toxic fumes of NOx.
Hazard Codes : N: Dangerous for the environment 
,
T: Toxic 
Risk Statements : 20/22: Harmful by inhalation and if swallowed
38: Irritating to the skin
50/53: Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
61: May cause harm to the unborn child
Safety Statements : 45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
53: Avoid exposure - obtain special instruction before use
60: This material and/or its container must be disposed of as hazardous waste
61: Avoid release to the environment. Refer to special instructions safety data sheet
RIDADR : UN 3082
RTECS : QE2705000
HazardClass : 6.1(b)
PackingGroup : III
Standards and Recommendations
ASSAY: 98.0% min
MOISTURE: 0.5% max
Specification
2,6-dimethyl-4-tridecylmorpholin (24602-86-6) is a yellow oily liquid and is stable under ordinary conditions. It is is insoluble in water, but soluble in most organic solvents.