Detail of > 2524-04-1
- CAS Number:
- 2524-04-1
- Name:
- Formula:
- C4H10ClO2PS
- Molecular Structure:
- Synonyms:
- Ethylphosphorochloridothioate ((EtO)2ClPS) (6CI);(Chlorodiethoxy)phosphine sulfide;Diethoxythiophosphoryl chloride;Diethyl phosphorochlorothioate;Diethylthiophosphoryl chloride;O,O-Diethyl thionophosphoric chloride;O,O-Diethyl thionophosphoryl chloride;O,O-Diethyl thiophosphorochloridate;
- Molecular Weight:
- 188.62
- EINECS:
- 219-755-4
- Density:
- 1.251 g/cm3
- Melting Point:
- - 75 °C
- Boiling Point:
- 187.5 °C at 760 mmHg
- Flash Point:
- 75.8 °C
- Solubility:
- immiscible with water
- Appearance:
- clear colorless to light yellow liquid
- Hazard Symbols:
T,
T+- Risk Codes:
- 23/24/25-34-26-21/22
- Safety:
- 23-26-36/37/39-45-28Details
- Transport Information:
- UN 2751 8/PG 2
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Reference
- Insecticidal and acaricidal thiophosphoric acid esters
-
Insecticidal and acaricidal thiophosphoric acid esters.
Nomura, Osami; Maeda, Kuniyasu; Ando, Meiki; Matsuda, Michihiko;
Watanabe, Hitoshi (Nippon Soda Co., Ltd., Japan). Japan. Kokai JP
52010422 26 Jan 1977 Showa, 10 pp. (Japanese). (Japan). CODEN:
JKXXAF. CLASS: IC: A01N009-36. 63857-66-9 which is the cas registry number is also used here. APPLICATION: JP 75-84118 9
Jul 1975. DOCUMENT TYPE: Patent CA Section: 5 (Agrochemicals)
Section cross-reference(s): 24
I [63857-66-9] was prepd. by treating
3-methoxy-5,5-dimethyl-2-cyclohexene-1-one oxime [63857-53-4] with
diethylthiophosphoryl chloride [2524-04-1]. I applied to houseflies at 5
.mu.g/fly caused 100% mortality in 24 h. Thirteen I derivs. were also
prepd. and their insecticidal and acaricidal activities presented.
.
- Insecticide and acaricide containing O,O-diethyl
O-[N-methoxy-2-nitrobenzimidoyl] thionophosphate ester
-
Insecticide and acaricide containing O,O-diethyl
O-[N-methoxy-2-nitrobenzimidoyl] thionophosphate ester.
Lorenz, Walter; Hammann, Ingeborg; Behrenz, Wolfgang; Homeyer,
Bernhard (Bayer A.-G., Ger.). Ger. Offen. DE 2544776 21 Apr 1977,
30 pp. (German). (Germany). CODEN: GWXXBX. CLASS: IC:
C07F009-165. APPLICATION: DE 75-2544776 7 Oct 1975.
DOCUMENT TYPE: Patent CA Section: 5 (Agrochemicals) Section
cross-reference(s): 25
The title compd. O,O-di-Et O-(N-methoxy-2-nitrobenzimidoyl)
thionophosphate (I) [63133-12-0], prepd. by reacting
N-methoxy-2-nitrobenzohydroxamic acid [63133-13-1] with O,O-diethyl
chloridothionophosphate [2524-04-1], is an acaricide and insecticide.
In a Tetranychus-resistance test, 0.1% I was 100% effective, while
similar thiophosphate compds. were ineffective.
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