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25324-56-5

Basic Information
CAS No.: 25324-56-5
Name: TIN PHOSPHIDE
Molecular Structure:
Molecular Structure of 25324-56-5 (TIN PHOSPHIDE)
Formula: PSn
Molecular Weight: 149.66
Synonyms: Tinphosphide (PSn) (6CI); Tin monophosphide
Density: g/cm3
Melting Point: decomposes [AES93]
Boiling Point: °Cat760mmHg
Flash Point: °C
Hazard Symbols: Flammable, dangerous fire risk. TLV: 2 mg(Sn)/m3.
Safety: A flammable solid. Reacts with moisture or acid fumes to liberate highly toxic phosphine gas. When heated to decomposition it emits toxic fumes of POx. See also PHOSPHINE, PHOSPHIDES, and TIN COMPOUNDS.
PSA: 46.94000
LogP: 0.04460
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Chemistry


IUPAC Name: phosphanylidynetin
Molecular Weight: 149.683761 g/mol
Molecular Formula: PSn 
Appreance: silver-white mass or lump solid
EINECS: 246-848-7
Heavy Atom Count: 2
Complexity: 10
Exact Mass: 150.875958
MonoIsotopic Mass: 150.875958
Canonical SMILES: P#[Sn]
InChI: InChI=1S/P.Sn
InChIKey: BSPSZRDIBCCYNN-UHFFFAOYSA-N
Synonyms of Tin(iv) phosphide (CAS NO.25324-56-5): Stannic phosphide ; Tin phosphide ; Tinmonophosphide ; Tinphosphide(snp)
 Mol File: 25324-56-5.mol

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

A flammable solid. Reacts with moisture or acid fumes to liberate highly toxic phosphine gas. When heated to decomposition it emits toxic fumes of POx. See also PHOSPHINE, PHOSPHIDES, and TIN COMPOUNDS.
RIDADR: UN3288
HazardClass: 6.1
PackingGroup: II
 

Standards and Recommendations

OSHA PEL: TWA 2 mg(Sn)/m3
ACGIH TLV: TWA 2 mg(Sn)/m3
DOT Classification:  4.3; Label: Dangerous When Wet, Poison

Specification

Fire Hazard: Tin(iv) phosphide (CAS NO.25324-56-5) can produce flammable and toxic gases if it is on contact with water. And it also may ignite on contact with moist air, heat, sparks or flames. Some react vigorously or explosively on contact with water.May re-ignite after fire is extinguished. Some are transported in highly flammable liquids. Containers may explode when heated. Run off may create fire or explosion hazard.
Health Hazard: Tin(iv) phosphide (CAS NO.25324-56-5) is highly toxic.If  people inhaled the toxic gas produced  by the Tin(iv) phosphide (CAS NO.25324-56-5) , it may be fatal. Also inhalation or contact with vapors, substance or decomposition products may cause severe injury or death. 
Reactivity Profile: Tin(iv) phosphide (CAS NO.25324-56-5) is a reducing agent. It slowly produces flammable or noxious gases if contact with water. Reacts quickly upon contact with acids to give the very toxic gas phosphine. Can react vigorously with oxidizing materials.