Detail of > 25597-16-4
- MSDS Download
- CAS Number:
- 25597-16-4
- Name:
2-Butenoic acid,4,4,4-trifluoro-, ethyl ester, (2E)-
- Superlist Name:
- Ethyl 4,4,4-trifluorocrotonate
- Formula:
- C6H7 F3 O2
- Molecular Structure:
- Synonyms:
- 2-Butenoicacid, 4,4,4-trifluoro-, ethyl ester, (E)-;(E)-Ethyl4,4,4-trifluorobut-2-enoate;Ethyl (E)-4,4,4-trifluorocrotonate;
- Molecular Weight:
- 168.11
- Density:
- 1.191 g/cm3
- Boiling Point:
- 114.5 °C at 760 mmHg
- Flash Point:
- 25.6 °C
- Appearance:
- Colorless and clear liquid
- Hazard Symbols:
Xi; 
F- Risk Codes:
- 10-36/37/38
- Safety:
- 16-26-27-28-36/37/39Details
- Transport Information:
- UN 3272 3/PG 3
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Reference
- Reaction of hydroxy and carbonyl compounds with sulfur tetrafluoride
- Reaction of hydroxy and carbonyl compounds with sulfur tetrafluoride. XII. Reactions of esters of aliphatic a- and b-hydroxy carboxylic acids with sulfur tetrafluoride. Motnyak, L. A.; Burmakov, A. I.; Kunshenko, B. V.; Neizvestnaya, T. A.; Alekseeva, L. A.; Yagupol'skii, L. M. (Odess. Politekh. Inst., Odessa, USSR). Zh. Org. Khim., 20(6), 1169-81 (Russian) 1984. CODEN: ZORKAE. ISSN: 0514-7492. 25597-16-4 which is the cas registry number of one of substances is just one of reagents here. DOCUMENT TYPE: Journal CA Section: 23 (Aliphatic Compounds) SF4 reacted with a- and b-hydroxy carboxylate esters to give fluoro esters and (alkoxycarbonyl)alkyl fluorosulfites, e.g., MeCH(OH)CO2Me reacted with SF4 to give 48% MeCHFCO2Me and 46% MeCH(OSOF)CO2Me. Also, MeOCF2CH(OH)CHFCO2Me reacted with SF4-NaF to give MeOCF2CH(OSOF)CHFCF2OMe. .
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