Detail of "26042-64-8"

CAS Number:
26042-64-8
Name:
Antimonate(1-),hexafluoro-, silver(1+) (1:1), (OC-6-11)-
Molecular Structure:
Formula:
Ag.F₆Sb
Molecular Weight:
343.62
Synonyms:
Antimonate(1-),hexafluoro-, silver(1+);Antimonate(1-), hexafluoro-, silver(1+), (OC-6-11)-(9CI);Silver fluoantimonate(V) (6CI);Silver hexafluoroantimonate(V) (7CI);Antimony silver fluoride (AgSbF6);Silver hexafluoroantimonate;Silverhexafluoroantimonate (AgSbF6);Silver hexafluoroantimonate(1-);Silvermono(hexafluoroantimonate);Silver(1+) hexafluoroantimonate;Silver(1+)hexafluoroantimonate(1-);Silver(I) hexafluoroantimonate;
EINECS:
247-429-1
Appearance:
White to pale yellow crystalline powder
Hazard Symbols:
Xn,N,C
Risk Codes:
20/22-51/53
Safety:
61 Details
Transport Information:
UN 3260 8/PG 2

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Cationic polymerization of 1,3-dioxolane and 1,3-dioxepane: Cationic polymerization of 1,3-dioxolane and 1,3-dioxepane. Application to graft and block copolymer synthesis. Reibel, Leonard C.; Durand, Claude P.; Franta, Emile (Cent. Rech. Macromol., CNRS, Strasbourg 67083, Fr.). Can. J. Chem., 63(1), 264-9 (English) 1985. CODEN: CJCHAG. ISSN: 0008-4042. DOCUMENT TYPE: Journal CA Section: 35 (Chemistry of Synthetic High Polymers) The cationic polymn. of 1,3-dioxolane [646-06-0] and 1,3-dioxepane [505-65-7] was investigated to prep. living polymers and then to use them for graft and block copolymn. Block copolymers [95892-53-8] contg. a central block of polydioxepane (I) and outer blocks of 1,2-dimethoxyethylene (II) were prepd. by addn. of II to living I in the presence of triflic anhydride [358-23-6]. Active polydioxolane reacted readily with polystyrene forming a graft copolymer [25853-29-6] in the absence of gel in the presence of BzCl [98-88-4] and AgSbF6 [26042-64-8].

Synthesis of poly(vinyl chloride-g-carbazole ethyl vinyl ether): Synthesis of poly(vinyl chloride-g-carbazole ethyl vinyl ether). Simionescu, C. I.; Rabia, I.; Grigoras, M. ("P. Poni" Inst. Macromol. Chem., Iasi 6600, Rom.). Cationic Polym. Relat. Processes, Proc. Int. Symp., 6th, Meeting Date 1983, 373-8. Edited by: Goethals, E. J.There are some reagents like 53807-86-6 is used in this study. Academic: London, UK. (English) 1984. CODEN: 52IJAA. DOCUMENT TYPE: Conference CA Section: 35 (Chemistry of Synthetic High Polymers) 2-N-Carbazolylethyl vinyl ether (I) was grafted on PVC [9002-86-2] by cooling a mixt. contg. the macroinitiator (PVC), I, and CH2Cl2 solvent, adding a precooled soln. of AgSbF6 [26042-64-8] in CH2Cl2 to start polymn. and adding precooled MeOH to terminate polymn. The polymers were characterized by IR spectra and gel-permeation chromatog. Grafting efficiency increased with decreasing temp. while I conversion decreased. This reflected a decreasing chain transfer to monomer at decreasing temps. The extent of grafting and I conversion increased with increasing labile allylic chlorine concns. in the polymer (caused by partial dehydrochlorination). .