Reference

Study of the initiating capacity of mixtures of aromatic amines and sulfimides in polymerization of triethylene glycol dimethacrylate

Study of the initiating capacity of mixtures of aromatic amines and sulfimides in polymerization of triethylene glycol dimethacrylate. Meiman, S. B.; Aronovich, D. A.; Pomerantseva, E. G.; Poduvalova, G. I.; Fokeeva, N.In this article, certain chemicals are used. One of their cas registry numbers is 109-16-0 V.; Sineokov, A. G. (USSR). Deposited Doc., SPSTL 918 Khp-D82, 11 pp. Avail. SPSTL (Russian) 1982. DOCUMENT TYPE: Report CA Section: 35 (Chemistry of Synthetic High Polymers) Arom. tertiary amines in mixts. with benzosulfimides formed charge-transfer complexes whose decay products were effective catalysts for polymn. of TGM-3 [109-16-0]. The most effective catalyst system was formed from dimethyl-p-toludine [99-97-8] with (PhSO2)2NH [2618-96-4]. No polymn. was obsd. in the presence of aliph. amines. A direct correlation was obsd. between the ability of the amines to form a complex with the benzosulfimides and the catalytic activity of the system. The effectiveness of the system was increased significantly by the addn. of cumyl hydroperoxide (I) [80-15-9]. The arom. amines or benzosulfimides alone did not accelerate the decompn. of I. .