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Detail of "26299-14-9"

  • MSDS Download
  • CAS Number:
  • 26299-14-9
  • Name:

  • Pyridinium chlorochromate

  • Molecular Structure:
  • Formula:
  • C5H5N.HCrO3Cl
  • Molecular Weight:
  • 215.55
  • Deleted CAS:
  • 147795-05-9|68017-35-6|68499-31-0
  • Synonyms:
  • PCC (oxidizing agent);Corey's reagent (oxidation reagent);Chromate(1-),chlorotrioxo-,(T-4)-,hydrogen,compd. with pyridine (1:1);Pyridinium chlorochromate(Adsorbed on Alumina);Pyridinium chlorochromate, PCC;
  • EINECS:
  • 247-595-5
  • Melting Point:
  • 205-208 °C(lit.)
  • Boiling Point:
  • 115.3 °C at 760 mmHg
  • Flash Point:
  • 20 °C
  • Appearance:
  • Orange crystalline powder
  • Hazard Symbols:
  • OxidizingO,ToxicT,DangerousN
  • Risk Codes:
  • 49-8-43-50/53-20/21/22
  • Safety:
  • 53-45-60-61-37-24-17-44-36/37/39-22 Details
  • Transport Information:
  • UN 1479 5.1/PG 2
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product name:Pyridinium chlorochromat molecular formula:C5H6NCLCrO3 molecular weight:215.56

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Reference

Controlled oxidation of collagen with pyridinium chlorochromate
Controlled oxidation of collagen with pyridinium chlorochromate. Sehgal, P. K.; Balasubramanian, K.; Joseph, K. Thomas (Cent. Leather Res. Inst., Madras, India). Leather Sci. (Madras), 31(2), 38-41 (English) 1984. CODEN: LESCA9. ISSN: 0023-9771. DOCUMENT TYPE: Journal CA Section: 45 (Industrial Organic Chemicals, Leather, Fats, and Waxes) The oxidn. of collagen by pyridinium chlorochromate [26299-14-9] is clearly shown by the decrease in the content of hydroxyamino acids. The intrinsic viscosity and denaturation temp. indicate that collagen is not denatured by this treatment. Fibril formation acceleration is obsd., and the fibrils are not redispersed to the extent of untreated collagen. The dissoln. temp. is significantly high in the treated collagen. The UV spectra shows intense carbonyl absorption, confirming conversion of OH groups to aldehydes and ketones.
Determination of some sulpha drugs and diuretics with pyridinium chlorochromate (PCC) reagent
Determination of some sulpha drugs and diuretics with pyridinium chlorochromate (PCC) reagent. Dubey, B. K.; Tiwari, A.Chemicals with cas numbers 26299-14-9 and 127-56-0 also play role. K.; Shukla, I. C. (Department of Chemistry, University of Allahabad, Allahabad 211002, India). National Academy Science Letters (India), 27(11 & 12), 413-418 (English) 2004 National Academy of Sciences, India. CODEN: NASLDX. ISSN: 0250-541X. DOCUMENT TYPE: Journal CA Section: 64 (Pharmaceutical Analysis) A simple titrimetric method was developed for milligram detn. of some sulfa drugs and diuretics e.g. sulfacetamide sodium, sulfamethoxazole, sulfadiazine, sulfaguanidine, acetazolamide, frusemide, and spironolactone in pure form and in their pharmaceutical prepn. Aliquots contg. 1-5 mg of the sample were allowed to react with excess of 3 ′ 10-2 N pyridinium chlorochromate (PCC) in the presence of 5 N H2SO4 for required reaction time at room temp. (25-30°C). After the reaction is over, the unconsumed reagent was back detd. iodometrically. The values of % error, SD and CV prove the method to be precise and reproducible. .
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