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| CAS No.: | 2631-37-0 |
|---|---|
| Name: | PROMECARB |
| Article Data: | 2 |
| Molecular Structure: | |
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|
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| Formula: | C12H17 N O2 |
| Molecular Weight: | 207.272 |
| Synonyms: | Carbamicacid, methyl-, m-cym-5-yl ester (7CI,8CI); Phenol, 3-methyl-5-(1-methylethyl)-,methylcarbamate (9CI); 3-Isopropyl-5-methylphenyl N-methylcarbamate;3-Isopropyl-5-methylphenyl methylcarbamate; 3-Methyl-5-isopropylphenylN-methylcarbamate; 3-Methyl-5-isopropylphenyl methylcarbamate; Carbamult; EP316; ITC; Minacide; Morton EP-316; NSC 35378; Promecarb; Sch 34615; Schering34615; m-Cym-5-yl methylcarbamate |
| Density: | 1.024g/cm3 |
| Melting Point: | 87-88ºC |
| Boiling Point: | 282°Cat760mmHg |
| Flash Point: | 124.3°C |
| Solubility: | 92mg/L(room temperature) |
| Hazard Symbols: | Toxic by ingestion. |
| Risk Codes: | 25-50/53 |
| Safety: | Poison by ingestion, intraperitoneal, intravenous, intramuscular, and subcutaneous routes. Moderately toxic by skin contact. An insecticide. When heated to decomposition it emits toxic fumes of NOx. See also CARBAMATES. |
| PSA: | 38.33000 |
| LogP: | 3.22750 |
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Chemistry
IUPAC Name: (3-Methyl-5-propan-2-ylphenyl) N-methylcarbamate
Synonyms: 3-Isopropyl-5-methylphenyl methylcarbamate ; 3-Isopropyl-5-methylphenyl-methylcarbamat ; 3-Methyl-5-(propan-2-yl)phenyl methylcarbamate ; Methylcarbamate de 3-isopropyl-5-méthylphényle
Product Categories: Alpha sort;CarbamatesPesticides&Metabolites;Insecticides;N-PAlphabetic;P;Pesticides;PON - PT
CAS NO: 2631-37-0
Molecular Formula of m-Cym-5-yl methylcarbamate (CAS NO.2631-37-0) : C12H17NO2
Molecular Weight of m-Cym-5-yl methylcarbamate (CAS NO.2631-37-0) : 207.27
Molecular Structure of m-Cym-5-yl methylcarbamate (CAS NO.2631-37-0) :
EINECS: 220-113-0
Mol File: 2631-37-0.mol
Merck : 13,7875
Index of Refraction: 1.507
Surface Tension: 34.3 dyne/cm
Density: 1.024 g/cm3
Flash Point: 124.3 °C
Enthalpy of Vaporization: 52.08 kJ/mol
Boiling Point: 282 °C at 760 mmHg
Vapour Pressure: 0.00345 mmHg at 25°C
Storage temp: 0-6°C
Appearance: Almost odorless, colorless crystalline solid
Uses
M-Cym-5-yl methylcarbamate (CAS NO.2631-37-0) is used as a non-systemic contact insecticide.
Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| bird - wild | LD50 | oral | 5mg/kg (5mg/kg) | Journal de Toxicologie Clinique et Experimentale. Vol. 6(3), Pg. 175, 1986. | |
| duck | LD50 | oral | 3500ug/kg (3.5mg/kg) | Pesticide Manual. Vol. 9, Pg. 709, 1991. | |
| guinea pig | LDLo | oral | 25mg/kg (25mg/kg) | Journal of Economic Entomology. Vol. 61, Pg. 1261, 1968. | |
| guinea pig | LDLo | subcutaneous | 25mg/kg (25mg/kg) | Journal of Economic Entomology. Vol. 61, Pg. 1261, 1968. | |
| mouse | LD50 | oral | 16mg/kg (16mg/kg) | Bulletin of the Entomological Society of America. Vol. 15, Pg. 131, 1969. | |
| quail | LD50 | oral | 78mg/kg (78mg/kg) | Pesticide Manual. Vol. 9, Pg. 709, 1991. | |
| rabbit | LD50 | skin | 11600uL/kg (11.6mL/kg) | "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc of Chemistry, 1983-86Vol. A338, Pg. 1983, | |
| rat | LC50 | inhalation | > 160mg/m3/4H (160mg/m3) | "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc of Chemistry, 1983-86Vol. A338, Pg. 1983, | |
| rat | LD50 | intramuscular | 44mg/kg (44mg/kg) | British Journal of Industrial Medicine. Vol. 22, Pg. 317, 1965. | |
| rat | LD50 | intraperitoneal | 27200ug/kg (27.2mg/kg) | BEHAVIORAL: GENERAL ANESTHETIC LUNGS, THORAX, OR RESPIRATION: DYSPNEA LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES | Bulletin of the World Health Organization. Vol. 44, Pg. 241, 1971. |
| rat | LD50 | intravenous | 5mg/kg (5mg/kg) | British Journal of Industrial Medicine. Vol. 22, Pg. 317, 1965. | |
| rat | LD50 | oral | 35mg/kg (35mg/kg) | Journal of Economic Entomology. Vol. 61, Pg. 743, 1968. | |
| rat | LD50 | skin | 450mg/kg (450mg/kg) | World Review of Pest Control. Vol. 9, Pg. 119, 1970. |
Consensus Reports
EPA Extremely Hazardous Substances List.
Safety Profile
Poison by ingestion, intraperitoneal, intravenous, intramuscular, and subcutaneous routes. Moderately toxic by skin contact. An insecticide. When heated to decomposition it emits toxic fumes of NOx. See also CARBAMATES.
Hazard Codes 
T,
N
Risk Statements 25-50/53
R25 :Toxic if swallowed.
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements 24-37-45-60-61
S24:Avoid contact with skin.
S37:Wear suitable gloves.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S60:This material and its container must be disposed of as hazardous waste.
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
RIDADR 2757
RTECS FB8050000
HazardClass 6.1(a)
PackingGroup II
Specification
1.Reactivity Profile: Promecarb is a carbamate ester. Carbamates are chemically similar to, but more reactive than amides. Like amides they form polymers such as polyurethane resins. Carbamates are incompatible with strong acids and bases, and especially incompatible with strong reducing agents such as hydrides. Flammable gaseous hydrogen is produced by the combination of active metals or nitrides with carbamates. Strongly oxidizing acids, peroxides, and hydroperoxides are incompatible with carbamates.
2.Health Hazard: Promecarb is highly toxic by ingestion and is absorbed through the intact skin. It is a reversible cholinesterase inhibitor and its effects are related to action on the nervous sysem.
3.Fire Hazard: (Non-Specific -- Carbamate Pesticide, Solid, n.o.s.) Container may explode in heat of fire. Fire and runoff from fire control water may produce irritating or poisonous gases. Hydrolyzed by alkalis. Stable. No changes observed on storage for 140 hours at122F.