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2687-25-4

Basic Information
CAS No.: 2687-25-4
Name: 2,3-DIAMINOTOLUENE
Article Data: 45
Molecular Structure:
Molecular Structure of 2687-25-4 (2,3-DIAMINOTOLUENE)
Formula: C7H10N2
Molecular Weight: 122.17
Synonyms: Toluene-2,3-diamine(7CI,8CI);1,2-Diamino-3-methylbenzene;1-Methyl-2,3-phenylenediamine;2,3-Diaminotoluene;2,3-Toluylenediamine;2,3-Tolylenediamine;2-Amino-3-methylaniline;3-Methyl-1,2-benzenediamine;3-Methyl-1,2-diaminobenzene;3-Methyl-1,2-phenylenediamine;3-Methyl-o-phenylenediamine;
EINECS: 220-248-5
Density: 1.107 g/cm 3
Melting Point: 59-65 °C(lit.)
Boiling Point: 255 °C at 760 mmHg
Flash Point: 131.1 °C
Appearance: brown powder
Hazard Symbols: IrritantXi; HarmfulXn
Risk Codes: 20/21/22-36/37/38
Safety: 26-36-36/37/39
Transport Information: UN 2811
PSA: 52.04000
LogP: 2.32180
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Chemistry

Molecular Formula:C7H10N2
Molar mass:122.1677 g/mol
Structure of 2,3-TOLYLENEDIAMINE(2687-25-4):
                                     
Synonyms of 2,3-TOLYLENEDIAMINE(2687-25-4):2,3-DIAMINOTOLUENE;Toluene-2,3-diamine;1,2-Benzenediamine, 3-methyl-;3-Methyl-o-phenylenediamine;3-Methyl-1,2-benzenediamine;3-Methyl-1,2-phenylenediamine;Toluene, 2,3-diamino-;
1,2-Diamino-3-methylbenzene
Density:1.107 g/cm3
Flash Point:131.1 °C 
Boiling Point:255 °C at 760 mmHg          
Index of Refraction:1.636
Vapour Pressure:0.0167 mmHg at 25°C
Melting point:59-65 °C(lit.)

Toxicity Data With Reference

1.   

ipr-mus LD50:286 mg/kg

   GENEA3    Genetica (The Hague). 26 (1985),109.
Carcinogenicity:2,3-TOLYLENEDIAMINE(2687-25-4)- Not listed as a carcinogen by IARC, NTP,ACGIH,  or CA Prop 65.
Other: The toxicological properties have not been fully investigated.See actual entry in RTECS for complete information.

Consensus Reports

2,3-TOLYLENEDIAMINE(2687-25-4) has been reported in EPA TSCA Inventory.

Safety Profile

Poison by intraperitoneal route. When heated to decomposition it emits toxic vapors of NOx.
Hazard Codes:Xn,Xi
Risk Statements:
20:  Harmful by inhalation
21:  Harmful in contact with skin
22:  Harmful if swallowed 
36:  Irritating to the eyes
37:  Irritating to the respiratory system
38:  Irritating to the skin
Safety Statements:
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36:  Wear suitable protective clothing 
37:  Wear suitable gloves
39:  Wear eye/face protection

Specification

Stability and Reactivity of 2,3-TOLYLENEDIAMINE(2687-25-4):
Conditions to Avoid: Incompatible materials.
Chemical Stability:Stable under normal temperatures and pressures.
Incompatibilities with Other Materials:strong acids;Strong oxidizing agents.
Hazardous Decomposition Products:carbon dioxide,Nitrogen oxides, Carbon monoxide.