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Detail of "2689-68-1"

  • CAS Number:
  • 2689-68-1
  • Name:
  • 3-Thiophenecarboxylicacid, tetrahydro-4-oxo-, methyl ester

  • Superlist Name:
  • Methyl 4-oxotetrahydrothiophene-3-carboxylate
  • Molecular Structure:
  • Formula:
  • C6H8O3S
  • Molecular Weight:
  • 160.19
  • Deleted CAS:
  • 99328-39-9
  • Synonyms:
  • 4-Carbomethoxy-2,3,4,5-tetrahydro-3-thiophenone;4-Carbomethoxy-3-thiophanone;4-Oxotetrahydrothiophene-3-carboxylic acid methylester;Methyl 4-oxo-2,3,4,5-tetrahydrothiophene-3-carboxylate;Methyl4-oxotetrahydrothienyl-3-carboxylate;Methyltetrahydro-4-oxo-3-thiophenecarboxylate;NSC 127560;Tetrahydro-4-oxo-3-thiophenecarboxylicacid methyl ester;Methyl 4-oxotetrahydrothiophene-3-carboxylate;
  • EINECS:
  • 220-256-9
  • Density:
  • 1.31 g/cm3
  • Boiling Point:
  • 248.4 °C at 760 mmHg
  • Flash Point:
  • 116.7 °C
  • Appearance:
  • Slight yellow to yellow crystalline powder
  • Hazard Symbols:
  • IrritantXi
  • Risk Codes:
  • 36/37/38
  • Safety:
  • 26-37/39 Details

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CAS No.2689-68-1 Methyl 4-oxotetrahydrothiophene-3-carboxylate

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CAS No.2689-68-1 Methyl 4-oxotetrahydrothiophene-3-carboxylate

Supplier:Shanghai Apichemical CO.,LTD [ China (Mainland)]

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CAS No.2689-68-1 Methyl 4-oxotetrahydrothiophene-3-carboxylate

Supplier:SHANGHAI ZEALING CHEMICAL CO., LTD. [ China (Mainland)]

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CAS No.2689-68-1 Methyl 4-oxotetrahydrothiophene-3-carboxylate

Supplier:Shenyang Dakang Pharmaceutical Technology Co. Ltd [ China (Mainland)]

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Reference

Alkyl 3-oxotetrahydrothiophenecarboxylates
Alkyl 3-oxotetrahydrothiophenecarboxylates. Waring, David Richard (Kodak Ltd., UK). Brit. UK Pat. Appl. GB 2122185 A1 11 Jan 1984, 4 pp. (English). (United Kingdom). CODEN: BAXXDU. CLASS: IC: C07D333-38. APPLICATION: GB 82-18261 24 Jun 1982. DOCUMENT TYPE: Patent CA Section: 27 (Heterocyclic Compounds (One Hetero Atom)) Sulfides RO2CCH2CH2SCH2CO2R (R = alkyl) were treated with alkali alkoxides to yield mixts. of thiophene derivs. 7400-45-5 and 2689-68-1 are also in the experiment. I and II. Thus, NaOMe in a THF-PhMe mixt. was treated with MeO2CCH2CH2SCH2CO2Me, the mixt. was stirred, and H2SO4 was added to give a mixt. of I- and II (R = Me). .
Dihydrothiophenecarboxylic acid esters and their herbicidal use
Dihydrothiophenecarboxylic acid esters and their herbicidal use. Acker, Rolf Dieter; Rossy, Phillip A.; Hamprecht, Gerhard; Wuerzer, Bruno (BASF A.-G. , Fed. Rep. Ger.). Ger. Offen. DE 3211851 A1 6 Oct 1983, 41 pp. (German). (Germany). CODEN: GWXXBX. CLASS: IC: C07D333-38; A01N047-36. APPLICATION: DE 82-3211851 31 Mar 1982. DOCUMENT TYPE: Patent CA Section: 27 (Heterocyclic Compounds (One Hetero Atom)) Section cross-reference(s): 5 Herbicidal (no data) I [R = alkenyl, alkynyl, cycloalkyl, (un)substituted alkyl, Ph, PhCH2; R1 = H, R] were prepd. Thus, 15.1 parts Me 1,5-dihydro-4-oxo-3-thiophenecarboxylate was condensed with 14.2 parts cyclohexylurea to give 20.3 parts I (R = cyclohexyl, R1 = Me).Except for chemicals metioned above, 88347-60-8 and 2689-68-1 are also used. .
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