Detail of "279-23-2"

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CAS Number:
279-23-2
Name:
Bicyclo[2.2.1]heptane
Molecular Structure:
Formula:
C₇H₁₂
Molecular Weight:
96.17
Synonyms:
Norbornane(6CI,7CI,8CI);1,4-Endomethylenecyclohexane;Cyclohexane, 1,4-endo-methylene-;NSC 91457;Norbornylane;Norcamphane;Norfenchane;Norsantane;
EINECS:
205-996-2
Density:
0.914 g/cm³
Melting Point:
85-88 °C(lit.)
Boiling Point:
112.6 °C at 760 mmHg
Appearance:
white solid

Display：

0.914g/cm3 112.6°C at 760 mmHg 25.4mmHg at 25°C

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Cleavage of homoallylic alcohols - a novel fragmentation reaction: Cleavage of homoallylic alcohols - a novel fragmentation reaction. Yadav, J. S.; Chawla, H. 63025-63-8 which is the cas registry number of one of substances is just one of reagents here. P. S.; Dev, Sukh (Malti-Chem Res. Cent., Vadodara, India). Tetrahedron Lett., (2), 201-4 (English) 1977. CODEN: TELEAY. DOCUMENT TYPE: Journal CA Section: 30 (Terpenoids) Section cross-reference(s): 24 Bicyclo[2.2.1]heptane homoallylic alcs. underwent ring cleavage by electrophilic addn. of Cl. E.g., camphene alc. I with Cl in CCl4 gave cyclopentene II, quant. .

Preparation of enantiopure norbornane ligands bearing both (2S,3S)-Bis(phosphinomethyl) and 7-syn-oxygen functional groups and an application to rhodium-catalyzed asymmetric hydrogenation: Preparation of enantiopure norbornane ligands bearing both (2S,3S)-Bis(phosphinomethyl) and 7-syn-oxygen functional groups and an application to rhodium-catalyzed asymmetric hydrogenation. Morimoto, Toshiaki; Yamazaki, Akira; Achiwa, Kazuo (School of Pharmaceutical Sciences, University of Shizuoka, Shizuoka 422-8526, Japan). Chemical & Pharmaceutical Bulletin, 52(11), 1367-1371 (English) 2004 Pharmaceutical Society of Japan. CODEN: CPBTAL. ISSN: 0009-2363. DOCUMENT TYPE: Journal CA Section: 24 (Alicyclic Compounds) Enantiopure bicyclo[2.2.1]heptane I (R = MeOCH2O) having both (2S,3S)-bis[(diphenylphosphino)methyl] and 7-syn-oxygen functional groups was synthesized via diastereoselective Diels-Alder reaction of di-(1R)-menthyl fumarate and 5-trimethylsilylcyclopentadiene followed by silver-promoted stereospecific frame rearrangement of a bromolactone intermediate. 60576-58-1 are also occured in this study. Bicyclo[2.2.1]heptane I (R = H) was prepd. similarly. Diphosphines I were used as chiral ligands for rhodium-catalyzed asym. hydrogenation of itaconic acid and (Z)-a-acetamidocinnamic acid. .