Detail of "2835-78-1"

CAS Number:
2835-78-1
Name:
Methanone,(3-aminophenyl)phenyl-
Superlist Name:
3-Aminobenzophenone
Molecular Structure:
Formula:
C13H11 N O
Molecular Weight:
197.23
Synonyms:
Benzophenone,3-amino- (6CI,7CI,8CI); (3-Aminophenyl)phenylmethanone; 3-Aminobenzophenone;3-Benzoylaniline; 3-Phenylcarbonylaniline; NSC 86511; m-Aminobenzophenone
EINECS:
220-614-4
Density:
1.161g/cm³
Melting Point:
85-87°C
Boiling Point:
381°Cat760mmHg
Flash Point:
184.2°C
Hazard Symbols:
Safety:
Hazard Codes Xi
Safety Statements 22-24/25-39-36
RTECS DJ0170000
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4-(5- and 7-)Benzoylindolin-2-ones and their pharmaceutical uses: 4-(5- and 7-)Benzoylindolin-2-ones and their pharmaceutical uses. Welstead, William J., Jr.; Moran, Henry W. (Robins, A. H., Co., Inc., USA). U.S. US 3975531 17 Aug 1976, 9 pp. (English). (United States of America). CODEN: USXXAM. CLASS: IC: C07D209-34. 2835-78-1 and 61085-30-1 which are cas registry numbers of chemicals are mentioned. NCL: 424274000. APPLICATION: US 72-254284 17 May 1972. DOCUMENT TYPE: Patent CA Section: 27 (Heterocyclic Compounds (One Hetero Atom)) Antiinflammatory (no data) benzoylindolinones I [R-R2 = H, R3 = 5-Bz, 7-Bz, 4-Bz; R = R1 = H, R2 = 5-Cl, 5-OMe, R3 = 7-Bz; R = SMe, R1 = R2 = H, R3 = 4-Bz, 7-Bz; R = H, SMe, R1 = Me, R2 = H, R3 = 7-Bz; R = H, SMe, R1 = R2 = H, R3 = 7-(4-ClC6H4CO)] were prepd. Thus, II (R4 = NH2) was treated with PhCH2COMe to give II (R4 = N:CMeCH2Ph) which rearranged to give III; III was ozonolyzed and the resulting 3,2-Bz(AcNH)C6H3CH2CO2Et cyclized with acid to I (R-R2 = H, R3 = 7-Bz). I (R-R2 = H, R3 = 5-Bz) was obtained by Friedel-Crafts benzoylation of I (R-R3 = H). .

Synthesis of photoaffinity probes of tautomycin: Synthesis of photoaffinity probes of tautomycin. Kurono, Masakuni; Shimomura, Aya; Isobe, Minoru (Graduate School of Bioagricultural Sciences, Laboratory of Organic Chemistry, Nagoya University, Chikusa, Nagoya 464-8601, Japan). Tetrahedron, 60(8), 1773-1780 (English) 2004 Elsevier Science B.V. CODEN: TETRAB. ISSN: 0040-4020. DOCUMENT TYPE: Journal CA Section: 26 (Biomolecules and Their Synthetic Analogs) Two types of photoaffinity probe, which possesses a benzophenone or a diazirine photophore on the 2-position of tautomycin, were prepd. in order to prove the details of binding site to PP1. Thus, reacting diazirinyl benzamide I with the dicarboxylic acid form of tautomycin gave diazirine photoaffinity probe II, 6% pure Z oxime and 31% pure E oxime. These photoaffinity probes were designed on the basis of the structure-activity relationship; thus, the diacid moiety is indispensable. 2835-78-1 is also in the experiment. The selective introduction of photolabeling units on the 2-position of tautomycin was achieved through the 2-oxime of tautomycin diacid. .