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Detail of "2926-30-9"

  • MSDS Download
  • CAS Number:
  • 2926-30-9
  • Name:

  • Methanesulfonic acid,1,1,1-trifluoro-, sodium salt (1:1)

  • Superlist Name:
  • Sodium trifluoromethanesulfonate
  • Molecular Structure:
  • Formula:
  • CF3HSO3Na
  • Molecular Weight:
  • 173.06
  • Synonyms:
  • Methanesulfonicacid, trifluoro-, sodium salt (8CI,9CI);Sodium perfluoromethane sulfonate;Sodium triflate;Sodium trifluoromethanesulfonate;Sodiumtrifluoromethylsulfonate;Trifluoromethanesulfonic acid sodium salt;Methanesulfonic acid, 1,1,1-trifluoro-, sodium salt (1:1);Sodium trifluoromethanesulfonate;
  • Melting Point:
  • 253-255 °C(lit.)
  • Boiling Point:
  • 162 °C at 760 mmHg
  • Solubility:
  • soluble in water
  • Appearance:
  • White to off-white powder
  • Hazard Symbols:
  • IrritantXi
  • Risk Codes:
  • 36/37/38-20/21/22
  • Safety:
  • 26-37/39 Details
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CAS No.2926-30-9 Sodium trifluoromethanesulfonateCompetitive Product

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CAS NO.: 2926-30-9 Structural Formula: Assay: 95% Package: 25kgs/plastic barrel

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Substitute for organic fluoride

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Reference

Cationic polymerization of tetrahydrofuran with fuming sulfuric acid initiator: Effects of superacid salts and aromatic compounds on Mn and yield of the polymer
Cationic polymerization of tetrahydrofuran with fuming sulfuric acid initiator: Effects of superacid salts and aromatic compounds on Mn and yield of the polymer. Tanaka, Yoshiaki (Wakayama Res. Lab., Kao Soap Co., Ltd., Wakayama, Japan). J. Macromol. Sci., Chem., A11(12), 2189-98 (English) 1977. CODEN: JMCHBD. ISSN: 0022-233X. DOCUMENT TYPE: Journal CA Section: 35 (Synthetic High Polymers) Superacid salts or arom. compds. increase the mol. wt. of poly(tetramethylene glycol) [25190-06-1] prepd. by bulk polymn. of THF in the presence of fuming H2SO4 and Na trifluoromethanesulfonate (I) [2926-30-9] at -5° to 0°. Perchlorates which were sol. in THF (such as Mg(ClO4)2 or Fe(ClO4)3) increased the mol. wt. whereas insol. ones did not increase mol. wt. As the I content in fuming H2SO4 was increased, mol. wt. and yield increased steadily. The polymer yield increased linearly with decreasing amts. of fuming H2SO4 in the presence of I, but in its absence, a max. was obsd. at ~60% polymer yield. Decreasing the amt. of initiator in the presence of a fixed ratio of fuming H2SO4 and I increased both mol. wt. and polymer yield.
Styrene dimers
Styrene dimers. Higashimura, Toshinobu; Masuda, Toshio; Sawamoto, Mitsuo; Nishii, Hideo (Japan ). Japan. Kokai JP 51115449 12 Oct 1976 Showa,8 pp. (Japanese). (Japan). CODEN: JKXXAF. CLASS: IC: C07C015-12. APPLICATION: JP 75-39744 3 Apr 1975. DOCUMENT TYPE: Patent CA Section: 25 (Noncondensed Aromatic Compounds) Styrene dimers were prepd. by dimerization of styrene or its C1-C3 mono- or dialkyl derivs.Several reagents such as 7601-90-3 is used here. at 0-150.degree. in the presence of sulfonate or perchlorate anions. Thus, a mixt. of 0.50 mole/l. PhCH:CH2 and 0.20 mmoles/l. CF3SO3H in C6H6 2 h at 50.degree. under N gave a product contg. 94% 1,3-diphenyl-1-butene with 95% conversion of PhCH:CH2. A mixt. of m-vinyltoluene and p-vinyltoluene was similarly dimerized to give a mixt. of 1,3-di-p-tolyl-, 1,3-di-m-tolyl-, 1-p-tolyl-3-m-tolyl-, and 1-m-tolyl-3-p-tolyl-1-butenes. CF3SO3Me-H2SO4, FSO3H, CF3SO3Na-H2SO4, MeSO3H, cyclohexanesulfonic acid, p-MeC6H4SO3H, Ac+ClO4-, Ph3C+ClO4-, HClO4, NaClO4-H2SO4, and Bu4N+ClO4--H2SO4 were also used instead of CF3SO3H. .
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