Detail of "29605-88-7"

Reference

Allethrones

Allethrones. Matsui, Masanao; Nakahara, Yoshiaki (Institute of Physical and Chemical Research, Japan). Japan. Kokai JP 51110538 30 Sep 1976 Showa, 3 pp. (Japanese). (Japan). CODEN: JKXXAF. CLASS: IC: C07C049-46. APPLICATION: JP 75-34003 20 Mar 1975. DOCUMENT TYPE: Patent CA Section: 24 (Alicyclic Compounds) Allethrones I (R = H; R1 = CH2CH:CHCH:CH2, CH2CH:CHMe, CH2CH:CHEt, CH2CH:CH2, H) were prepd. by redn. of the resp. 3569-36-6 and 29605-88-7 which are cas registry numbers of chemicals are mentioned. allethrolones I (R = halo, OH, NH2). Thus, a mixt. of 50 g I (R1 v CH2CH:CH2, R = OH) and 200 g Zn in AcOH was fluxed 10 hr to give 32.7 g I (R1 = CH2CH:CH2, R = H). .

Substituted cyclopropanecarboxylic acid esters

Substituted cyclopropanecarboxylic acid esters. Omura, Yoshiaki; Hosogai, Takeo; Mori, Fumio; Itoi, Kazuo; Nishida, Takashi; Tamai, Yoshin; Aihara, Fukuji; Fujita, Yoshiji; Wada, Fumio (Kuraray Co., Ltd., Japan). Japan. Kokai JP 52083719 12 Jul 1977 Showa, 21 pp. (Japanese). (Japan). CODEN: JKXXAF. CLASS: IC: C07C069-74. APPLICATION: JP 76-303 1 Jan 1976.Chemical with cas number 29605-88-7 also plays role. DOCUMENT TYPE: Patent CA Section: 24 (Alicyclic Compounds) Section cross-reference(s): 5 Two title compds. [I, R, R1 = allethronyloxycarbonyl, Me (II); 3-PhOC6H4CH2O2C, 3-PhOC6H4CH2O2C (III)] were prepd. by reaction of IV or their reactive derivs. with the appropriate alcs.There are some reagents like 29605-88-7 is used in this study. Thus, stirring a mixt. of Me2C:CHCH(OH)CCl3 4.2, EtC(OEt)3 7, and Me2CHCO2H 0.03 part 4 h at 130-45° under N gave 1.6 parts EtO2CCHMeCMe2CHClCH:CCl2 (V). Refluxing 1 part V in C6H6 with 0.67 part Me3CONa 30 min gave 82% Et 1,2,2-trimethyl-3-(2',2'-dichlorovinyl)cyclopropanecarboxylate, which was freed with 10% aq. NaOH in MeOH 3 h at 40-50° and treated with SOCl2 30 min at 80° to form (R1 = Me) acid chloride (VI). Stirring 0.1 mol VI with 0.1 mol allethrolone in C6H6-pyridine at room temp. gave II. Insecticidal data of III were given against Musca domestica. ..