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298-06-6

Basic Information
CAS No.: 298-06-6
Name: Diethylphosphorodithioate
Article Data: 55
Molecular Structure:
Molecular Structure of 298-06-6 (Diethylphosphorodithioate)
Formula: C4H11O2PS2
Molecular Weight: 186.236
Synonyms: Di-O-ethyldithiophosphate;Dithiophosphoric acid O,O-diethyl ester;NSC 171184;O,O-Diethyl dithiophosphate;O,O-Diethyl dithiophosphoric acid ester;O,O-Diethyl hydrogen phosphorodithioate;O,O-Diethyl phosphorodithioate;O,O-Diethyl thiolothionophosphate;O,O'-Diethyl dithiophosphate;O,O'-Diethylhydrogen dithiophosphate;
EINECS: 206-055-9
Density: 1.214 g/cm3
Melting Point: <0 °C
Boiling Point: 232.669 °C at 760 mmHg
Flash Point: 94.515 °C
Solubility: 330g/L at 25℃
Hazard Symbols: ToxicT
Risk Codes: 23/24/25-34
Safety: 26-36/37/39-45
Transport Information: UN 3265 8/PG 2
PSA: 99.16000
LogP: 2.86430
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Chemistry

IUPAC Name: Diethoxy-sulfanyl-sulfanylidene-λ5-phosphane
Synonyms: Diethyl phosphorodithioic acid ; Di-o-ethyldithiophosphate ; EP-1 ; Kyselina O,O-diethyldithiofosforecna ; Kyselina O,O-diethyldithiofosforecna ; Kyselina O,O-diethyldithiofosforecna(czech) ; O,O'-Diethylhydrogendithiophosphate ; O,O-Diethyl dithiophosphoric acid
Product Categories: Pharmaceutical Intermediates;Organic Building Blocks;Organic Phosphates/Phosphites;Phosphorus Compounds
CAS NO: 298-06-6
Molecular Formula: C4H11O2PS2
Molecular Weight: 186.23
Molecular Structure:
EINECS: 206-055-9
Mol File: 298-06-6.mol
Index of Refraction: 1.513
Surface Tension: 44.4 dyne/cm
Density: 1.214 g/cm3
Flash Point: 94.5 °C
Enthalpy of Vaporization: 45.03 kJ/mol
Boiling Point: 232.7 °C at 760 mmHg
Vapour Pressure: 0.0887 mmHg at 25°C
Melting point: <0°C storage temp. 2-8°C
Nature: Pure Phosphorodithioic acid,O,O-diethyl ester (CAS NO.298-06-6) is a colorless transparent oily liquid, industrial products, is the brown liquid, flammable, fetid odor
Solubility: Phosphorodithioic acid,O,O-diethyl ester (CAS NO.298-06-6) is soluble in water and organic solvents.

Uses

 Phosphorodithioic acid,O,O-diethyl ester (CAS NO.298-06-6) is pesticide intermediates, for the preparation of phorate and ethyl Phenthoate and other pesticides.

Production

derived from reaction of Ethanol with Phosphorus pentasulfide.

Toxicity Data With Reference

1.    

skn-rbt 500 mg/24H MOD

    28ZPAK    Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku Marhold, J.V.,Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha,Czechoslovakia.: 1972,212.
2.    

eye-rbt 50 µg/24H SEV

    28ZPAK    Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku Marhold, J.V.,Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha,Czechoslovakia.: 1972,212.
3.    

orl-rat LD50:4510 mg/kg

    28ZPAK    Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku Marhold, J.V.,Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha,Czechoslovakia.: 1972,212.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Mildly toxic by ingestion. A skin and severe eye irritant. When heated to decomposition it emits very toxic fumes of POx and SOx. See also ESTERS.
Hazard Codes ToxicT
Risk Statements 23/24/25-34 
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed. 
R34:Causes burns.
Safety Statements 26-36/37/39-45
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
RIDADR UN 3265 8/PG 2
WGK Germany 3
RTECS TD7350000
F 10-13-23
HazardClass 8
PackingGroup III