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Detail of "30547-28-5"

  • CAS Number:
  • 30547-28-5
  • Name:
  • dibutan-2-yl-oxo-tin

  • Molecular Structure:
  • Formula:
  • C8H18OSn
  • Molecular Weight:
  • 248.9379
  • Density:
  • g/cm3
  • Boiling Point:
  • °Cat760mmHg
  • Flash Point:
  • °C

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Reference

Steric effects on the formation of isolable products in the reactions of dibutyltin oxides with carboxylic acids
Steric effects on the formation of isolable products in the reactions of dibutyltin oxides with carboxylic acids. Mokal, V. B.; Jain, V. K. (Chem. Div., Bhabha At. Res. Cent., Trombay, Bombay - 400 085, India). J. Organomet. Chem., 441(2), 215-26 (English) 1992. CODEN: JORCAI. ISSN: 0022-328X. DOCUMENT TYPE: Journal CA Section: 29 (Organometallic and Organometalloidal Compounds) Reaction of dibutyltin oxides xBu2SnO [x = n (normal), i (iso), s (secondary) and t (tertiary)] with carboxylic acids (RCOOH; R = Me, Et, Me2CH, Me3C) in 1:1 and 1:2 stoichiometry were investigated. The products formed in these reactions were characterized by elemental analyses, IR and NMR (1H, 13C and 119Sn) data. Reactions in 1:2 stoichiometry afforded dibutyltin dicarboxylates which have six-coordinate tin atoms. Steric effects of the Bu group and the R group of the carboxylate ligand play an important role in 1:1 reactions. Dicarboxylatotetraorganostannoxanes were formed with Bu2SnO while hydroxo complexes [tert-Bu2Sn(m-OH)(OOCR)]2 were the sole products with tert-Bu2SnO.Some commonly used reagents like 30547-28-5 is used in this experiment. The stereochem. of all these complexes is discussed on the basis of NMR data. .
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