Detail of "3109-63-5"

Reference

Electrically conductive oligophenyls and their use

Electrically conductive oligophenyls and their use. Wegner, Gerhard; Eiffler, Juergen; Wieners, Gerhard; Monkenbusch, Michael; Naarmann, Herbert (BASF A.-G. , Fed. Rep. 429-42-5 and 89230-92-2 are also occured in this study. Ger.). Ger. Offen. DE 3210546 A1 6 Oct 1983, 17 pp. (German). (Germany). CODEN: GWXXBX. CLASS: IC: C08G061-10; C08F008-30; C08L065-02; C08K005-23. APPLICATION: DE 82-3210546 23 Mar 1982. DOCUMENT TYPE: Patent CA Section: 37 (Plastics Manufacture and Processing) Section cross-reference(s): 36 Elec. conductors are prepd. by doping oligophenyls and/or low-mol.-wt., arom. diazonium salts with conductive complex salts electrochem., preferably anodically, in polar org. solvents. Thus, electrolysis of an MeCN soln. of 0.01% biphenyl [92-52-4] and 0.02% Bu4N+PF6- [3109-63-5] at -30°, 10 V, and 5 mA for 16 h gave 520 mg red product with elec. cond. >0.1 W-1cm-1. .

Primary processes of the radiation-induced cationic polymerization of a-methylstyrene enhanced by triphenylsulfonium hexafluorophosphate

Primary processes of the radiation-induced cationic polymerization of a-methylstyrene enhanced by triphenylsulfonium hexafluorophosphate. Mah, Soukil; Yamamoto, Yukio; Hayashi, Koichiro (Inst. Sci. Ind. Res., Osaka Univ. 98-83-9 and 57835-99-1 are cas registry numbers. These chemicals are also mentioned in this article., Osaka 567, Japan). Radiat. Phys. Chem., 23(1-2), 137-41 (English) 1984. CODEN: RPCHDM. ISSN: 0146-5724. DOCUMENT TYPE: Journal CA Section: 35 (Chemistry of Synthetic High Polymers) Primary processes in the radiochem., cationic polymn. of a-methylstyrene [98-83-9] in CH2Cl2 contg. the catalyst Ph3S+ PF6- [57835-99-1] were studied by pulse radiolysis. The yield and lifetime of a-methylstyrene dimer radical cations were increased by the catalyst, owing to stabilization to neutralization by ion pair formation. The effect of Bu4N+ PF6- [3109-63-5] was similar, but it did not enhance polymn., probably owing to inhibition by the radiolysis product Bu3N. The results are compared with previous data for Ph2I+ PF6-, which also enhances polymn. .