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| CAS No.: | 3144-74-9 |
|---|---|
| Name: | CHLOROMETHYLDIMETHYLSILANE |
| Article Data: | 18 |
| Molecular Structure: | |
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|
|
| Formula: | C3H9ClSi |
| Molecular Weight: | 108.643 |
| Synonyms: | (Chloromethyl)dimethylsilane;Dimethyl(chloromethyl)silane;Dimethylsilylmethyl chloride;NSC 96776; |
| EINECS: | 221-556-2 |
| Density: | 0.894 g/mL at 25 °C(lit.) |
| Melting Point: | <0 °C |
| Boiling Point: | 81.6 °C at 760 mmHg |
| Flash Point: | 10 °F |
| Hazard Symbols: |
 F
|
| Risk Codes: | 11 |
| Safety: | 7-16-29-33 |
| Transport Information: | UN 1993 3/PG 2 |
| PSA: | 0.00000 |
| LogP: | 1.66940 |
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| Conditions | Yield |
|---|---|
| With lithium aluminium tetrahydride In dibutyl ether under 0.8 - 3.8 Torr; | 92% |
| Stage #1: Chloro(chloromethyl)dimethylsilane With lithium aluminium tetrahydride; diethylene glycol dibutyl ether at 2 - 45℃; Inert atmosphere; Stage #2: With hydrogenchloride In water at 2 - 10℃; pH=< 2; | 86% |
| With lithium aluminium tetrahydride In diethyl ether at 0℃; | 78% |
| Conditions | Yield |
|---|---|
| With platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex In toluene at 40℃; for 16h; Inert atmosphere; Schlenk technique; | 99% |
- 3144-74-9
chloromethyldimethylsilane
- 152339-15-6
1,3,5-Tris-(1,1-diallyl-but-3-enyl)-benzene
| Conditions | Yield |
|---|---|
| With bis(η2:η2-1,3-divinyltetramethyl)platinum(0) In diethyl ether; xylene at 20℃; for 72h; | 98% |
| chloroplatinic acid 1,1,3,3-tetramethyl-1,3-divinyldisiloxane complex at 20℃; for 24h; | |
| Kartsted catalyst In diethyl ether at 20℃; for 13h; |
- 3144-74-9
chloromethyldimethylsilane
| Conditions | Yield |
|---|---|
| With platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex In toluene at 25 - 40℃; for 16h; Inert atmosphere; | 95% |
| Conditions | Yield |
|---|---|
| dihydrogen hexachloroplatinate In toluene at 20℃; | 94% |
- 3144-74-9
chloromethyldimethylsilane
- 57618-47-0
5-benzyloxy-1-pentyne
- 1345668-23-6
(5-(benzyloxy)pent-1-en-2-yl)(chloromethyl)dimethylsilane
| Conditions | Yield |
|---|---|
| With cyclopentadienylruthenium(II) trisacetonitrile hexafluorophosphate In acetone at 5℃; for 2h; Inert atmosphere; Cooling; | 94% |
- 3144-74-9
chloromethyldimethylsilane
- 224191-80-4
4-triallylmethylphenol
- 387339-00-6
4-{4-(chloromethyl-dimethyl-silanyl)-1,1-bis-[3-(chloromethyl-dimethyl-silanyl)-propyl]-butyl}-phenol
| Conditions | Yield |
|---|---|
| In diethyl ether at 20℃; for 48h; | 91% |
| chloroplatinic acid 1,1,3,3-tetramethyl-1,3-divinyldisiloxane complex In diethyl ether at 20 - 35℃; for 48h; | 85% |
| chloroplatinic acid 1,1,3,3-tetramethyl-1,3-divinyldisiloxane complex In diethyl ether at 20 - 50℃; for 48h; | 85% |
| With chloroplatinic acid 1,1,3,3-tetramethyl-1,3-divinyldisiloxane complex In tetrahydrofuran at 40℃; for 24h; Inert atmosphere; | |
| With platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex In diethyl ether at 20℃; for 24h; |
- 3144-74-9
chloromethyldimethylsilane
- 124-38-9
carbon dioxide
- 109-89-7
diethylamine
- 64128-88-7
(chloromethyl)dimethylsilyl diethylcarbamate
| Conditions | Yield |
|---|---|
| at 50℃; for 5h; N-siloxycarbonylation; | 90.8% |
| Conditions | Yield |
|---|---|
| In hexane for 10h; amination; Heating; | 90.7% |
- 3144-74-9
chloromethyldimethylsilane
| Conditions | Yield |
|---|---|
| With platinum divinyltetramethyldisiloxane In tetrahydrofuran at 54℃; for 22h; | 90% |
- Total:23 Page 1 of 1 1
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Specification
The CAS register number of Silane,(chloromethyl)dimethyl- is 3144-74-9. It also can be called as Dimethyl(chloromethyl)silane and the systematic name about this chemical is (chloromethyl)(dimethyl)silane. The molecular formula about this chemical is C3H9ClSi and the molecular weight is 108.64. It belongs to the following product categories which include Organometallic Reagents; Organosilicon; Others and so on.
Physical properties about Silane,(chloromethyl)dimethyl- are: (1)ACD/LogP: 1.75; (2)ACD/LogD (pH 5.5): 1.75; (3)ACD/LogD (pH 7.4): 1.75; (4)ACD/BCF (pH 5.5): 12.57; (5)ACD/BCF (pH 7.4): 12.57; (6)ACD/KOC (pH 5.5): 213.04; (7)ACD/KOC (pH 7.4): 213.04; (8)#Freely Rotating Bonds: 1; (9)Enthalpy of Vaporization: 30.89 kJ/mol; (10)Boiling Point: 81.6 °C at 760 mmHg; (11)Vapour Pressure: 90.3 mmHg at 25°C.
Preparation: this chemical can be prepared by chloro-chloromethyl-dimethyl-silane. This reaction will need reagent LiAlH4.
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Uses of Silane,(chloromethyl)dimethyl-: it can be used to produce 1-chloro-2,2,5,5-tetramethyl-2-silahexane with 3,3-dimethyl-but-1-ene. This reaction will need reagent H2PtCl6.
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When you are using this chemical, please be cautious about it as the following:
This chemical is highly flammable. If you want to store this chemical, please keep container tightly closed and keep away from sources of ignition. If you want to use it, please do not empty into drains. When you are using it, please take precautionary measures against static discharges.
You can still convert the following datas into molecular structure:
(1)SMILES: ClC[SiH](C)C
(2)InChI: InChI=1/C3H9ClSi/c1-5(2)3-4/h5H,3H2,1-2H3
(3)InChIKey: BHLKIZCNPYDMOY-UHFFFAOYAC
(4)Std. InChI: InChI=1S/C3H9ClSi/c1-5(2)3-4/h5H,3H2,1-2H3
(5)Std. InChIKey: BHLKIZCNPYDMOY-UHFFFAOYSA-N