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CAS No.: | 3159-98-6 |
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Name: | 1,4-bis(2-hydroperoxypropan-2-yl)benzene |
Article Data: | 14 |
Molecular Structure: | |
Formula: | C12H18 O4 |
Molecular Weight: | 226.273 |
Synonyms: | Hydroperoxide,(p-phenylenediisopropylidene)di- (7CI,8CI); Hydroperoxide,[1,4-phenylenebis(1-methylethylidene)]bis- (9CI);(p-Phenylenediisopropylidene)dihydroperoxide;1,4-Bis(1-hydroperoxy-1-methylethyl)benzene;1,4-Bis(2-hydroperoxy-2-propyl)benzene; 1,4-Diisopropylbenzenebishydroperoxide; 1,4-Diisopropylbenzene dihydroperoxide; Bis(2-hydroperoxide-2-propyl)benzene;p-Bis(hydroperoxyisopropyl)benzene; p-Diisopropylbenzene bis(hydroperoxide);p-Diisopropylbenzene dihydroperoxide; p-Diisopropylphenyl dihydroperoxide; a,a'-Dihydroperoxy-p-diisopropylbenzene |
Density: | 1.145g/cm3 |
Boiling Point: | 403.2°Cat760mmHg |
Flash Point: | 197.7°C |
PSA: | 58.92000 |
LogP: | 3.13600 |
Conditions | Yield |
---|---|
With sulfuric acid; dihydrogen peroxide In toluene at 50℃; for 5h; | 99% |
1,4-bis(1-methylethyl)benzene
A
1-(4-isopropyl-phenyl)-1-methyl-ethyl hydroperoxide
B
p-diisopropylbenzene dihydroperoxide
Conditions | Yield |
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With calcium hydroxide; air; manganese(II) at 112℃; | |
liquid phase -oxidation; |
Conditions | Yield |
---|---|
With sodium hydroxide; 1-(4-isopropyl-phenyl)-1-methyl-ethyl hydroperoxide; oxygen at 90℃; Reagens 4: Stearinsaeure; | |
With air at 90℃; | |
With air; 1-(4-isopropyl-phenyl)-1-methyl-ethyl hydroperoxide at 110℃; |
1,4-bis(1-methylethyl)benzene
A
1-(4-isopropyl-phenyl)-1-methyl-ethyl hydroperoxide
B
p-diisopropylbenzene dihydroperoxide
Conditions | Yield |
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at 85℃; Kinetics; | |
at 110℃; Kinetics; |
Conditions | Yield |
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With methanol; sodium carbonate | |
With triethylamine at 110 - 120℃; |
Conditions | Yield |
---|---|
With phosphoric acid | |
With sulfuric acid | |
With sulfuric acid; acetone |
p-diisopropylbenzene dihydroperoxide
A
α,α-dimethyl-p-isopropylbenzyl alcohol
B
α,α,α',α'-tetramethyl-1,4-benzenedimethanol
C
1-(4-isopropyl-phenyl)-1-methyl-ethyl hydroperoxide
D
hydroxyhydroperoxide of p-diisopropylbenzene
Conditions | Yield |
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barium naphthenate In various solvent(s) at 120℃; Product distribution; Rate constant; other temperature; other catalysts; the catalysts conc.; activity of catal;; | A 2.7 (unit not given) B 97.3 (unit not given) C 0.048 mol D n/a |