CAS No.3162-96-7,a-D-Glucopyranoside,methyl4,6-O-(phenylmethylene)- Suppliers

Detail of "3162-96-7"

CAS Number:

3162-96-7

Name:

a-D-Glucopyranoside,methyl4,6-O-(phenylmethylene)-

Superlist Name:

Methyl 4,6-O-benzylidene-alpha-D-glucopyranoside

Molecular Structure:

Formula:

C₁₄H₁₈O₆

Molecular Weight:

282.29

Synonyms:

Glucopyranoside,methyl 4,6-O-benzylidene-, a-D- (6CI,7CI,8CI);(+)-(4,6-O-Benzylidene)methyl-a-D-glucopyranoside;α-D-glucopyranoside, methyl 4,6-O-(phenylmethylene)-;

EINECS:

221-615-2

Density:

1.36 g/cm³

Melting Point:

164-167 °C

Boiling Point:

473 °C at 760 mmHg

Flash Point:

239.8 °C

Appearance:

White crystalline solid

Hazard Symbols:

Risk Codes:

20/21/22-34

Safety:

22-24/25-45-36/37/39-27-26 Details

Reference

A novel observation on Koenigs-Knorr condensation of 2,3,4,6-tetra-O-acetyl-a-D-glucopyranosyl bromide with methyl 4,6-O-benzylidene-a-D-glucopyranoside: A novel observation on Koenigs-Knorr condensation of 2,3,4,6-tetra-O-acetyl-a-D-glucopyranosyl bromide with methyl 4,6-O-benzylidene-a-D-glucopyranoside. Temeriusz, Andrzej; Piekarska, Boguslawa; Radomski, Jan; Stepinski, Janusz (Inst. Fundam. Probl. Chem., Polytech. Univ., Warsaw 02093, Pol.). Pol. J. Chem., 56(1), 141-7 (English) 1982. CODEN: PJCHDQ.In this experiment, several chemicals are used like 7115-19-7 and 3162-96-7 DOCUMENT TYPE: Journal CA Section: 33 (Carbohydrates) Oligosaccharides I [R1 = a-D-glucopyranosyl, R2 = R3 = H; R1 = R2 = H, R3 = b-D-glucopyranosyl (Q); R1 = Q, R2 = R3 = H; R1 = R3 = H, R2 = Q; R1 = R2 = Q, R3 = H; R1 = R3 = Q, R2 = H] and b,b-trehalose were identified as products of the title reaction in ClCH2CH2Cl in the presence of Ag carbonate, followed by deprotection. .

New method of benzylation of hindered glucosidic hydroxyl groups: New method of benzylation of hindered glucosidic hydroxyl groups. Czernecki, S.; Georgoulis, C.; Provelenghiou, C.; Fusey, G. (Lab. Cinet. Mec. React.Some commonly used reagents like 18685-18-2 and 3162-96-7 are used in this experiment. Org., Univ. Pierre Marie Curie, Paris, Fr.). Tetrahedron Lett., (39), 3535-6 (French) 1976. CODEN: TELEAY. DOCUMENT TYPE: Journal CA Section: 33 (Carbohydrates) Glycosides were benzylated rapidly and quant. with common reactants under mild conditions. E.g., a soln. of I (R = H) in THF and NaH with Bu4NI and PhCH2Br for 165 min at 20.degree. gave, after addn. of florisil, the benzyl ether I (R = CH2Ph). .

Detail of "3162-96-7"

a-D-Glucopyranoside,methyl4,6-O-(phenylmethylene)-

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CAS No.3162-96-7 Methyl 4,6-O-benzylidene-alpha-D-glucopyranoside

CAS No.3162-96-7 Methyl 4,6-O-benzylidene-alpha-D-glucopyranoside

CAS No.3162-96-7 Methyl 4,6-O-benzylidene-alpha-D-glucopyranoside

CAS No.3162-96-7 Methyl 4,6-O-benzylidene-alpha-D-glucopyranoside

CAS No.3162-96-7 Methyl 4,6-O-benzylidene-alpha-D-glucopyranoside

CAS No.3162-96-7 Methyl 4,6-O-benzylidene-alpha-D-glucopyranoside

CAS No.3162-96-7 Methyl 4,6-O-benzylidene-alpha-D-glucopyranoside

CAS No.3162-96-7 Methyl 4,6-O-benzylidene-alpha-D-glucopyranoside

CAS No.3162-96-7 Methyl 4,6-O-benzylidene-alpha-D-glucopyranoside

CAS No.3162-96-7 Methyl 4,6-O-benzylidene-alpha-D-glucopyranoside

Reference