Detail of "3195-24-2"

MSDS Download
CAS Number:
3195-24-2
Name:
Propanedioic acid,2,2-di-2-propen-1-yl-, 1,3-diethyl ester
Molecular Structure:
Formula:
C₁₃H₂₀O₄
Molecular Weight:
240.3
Synonyms:
NSC 46842;Diethyl diallylpropanedioate;2,2-(Diallyl)malonic acid diethyl ester;NSC 30683;Malonicacid, diallyl-, diethyl ester (6CI,7CI,8CI);Propanedioic acid, di-2-propenyl-,diethyl ester (9CI);Di-2-propenylpropanedioic acid diethyl ester;Diethyl 2,2-diallylmalonate;Diethyl diallylmalonate;
EINECS:
221-696-4
Density:
0.999 g/cm³
Boiling Point:
243.499 °C at 760 mmHg
Flash Point:
106.728 °C
Hazard Symbols:
Xi
Risk Codes:
36/37/38
Safety:
26-37/39 Details

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A pyridine-containing ruthenium-indenylidene complex: Synthesis and activity in ring-closing metathesis: All Rights Reserved. A pyridine-containing ruthenium-indenylidene complex: Synthesis and activity in ring-closing metathesis. Clavier, Herve; Petersen, Jeffrey L.; Nolan, Steven P. (Department of Chemistry, University of New Orleans, New Orleans, LA 70148, USA). Journal of Organometallic Chemistry, 691(24-25), 5444-5447 (English) 2006 Elsevier Ltd. CODEN: JORCAI. ISSN: 0022-328X. DOCUMENT TYPE: Journal CA Section: 45 (Industrial Organic Chemicals, Leather, Fats, and Waxes) Section cross-reference(s): 24, 27, 29 The reaction of Cl2Ru(PCy3)2(3-phenylindenylidene) with excess pyridine leads to the pyridine-contg. ruthenium-based complex: Cl2Ru(PCy3)(Py)2(3-phenylindenylidene) in good yield. This complex was fully characterized and evaluated as catalyst in ring-closing metathesis reactions. The moderate activity was examd.In this experiment, several chemicals are used like 250220-36-1 and 3195-24-2 by kinetic studies using several substrates and different reaction conditions. .

Triethylsilane-Indium(III) Chloride System as a Radical Reagent: Triethylsilane-Indium(III) Chloride System as a Radical Reagent. Hayashi, Naoki; Shibata, Ikuya; Baba, Akio (Department of Molecular Chemistry, Science and Technology Center for Atoms, Molecules and Ions Control (STAMIC), Graduate School of Engineering, Osaka University, Suita, Osaka 565-0871, Japan). Organic Letters, 6(26), 4981-4983 (English) 2004 American Chemical Society. CODEN: ORLEF7. ISSN: 1523-7060. DOCUMENT TYPE: Journal CA Section: 21 (General Organic Chemistry) A novel generation method of indium hydride (Cl2InH) was found by the transmetalation of InCl3 with Et3SiH. In the intramol. cyclization of enynes, the previously reported system (NaBH4-InCl3) has a problem of side reactions with the coexistent borane. In contrast, the problem was solved by the presented system, which affords effective hydroindation of alkynes. E.g., radical redn. of PhCYCH by InCl3/Et3SiH/Et3B gave 90% PhCH:CH2. E.g., redn. 3195-24-2 and 645-49-8 which are cas registry numbers of substances are two of reagents here. and intramol. cyclization of enyne CHYCCH2NTsCH2CH:CH2 gave 7% CH2:CHCH2NTsCH2CH:CH2 and 58% pyrrole deriv. I. .