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Detail of > 31954-27-5

  • CAS Number:
  • 31954-27-5
  • Name:
  • Glycine,N-[(1,1-dimethylethoxy)carbonyl]-, methyl ester

  • Superlist Name:
  • Methyl N-(tert-butoxycarbonyl)glycinate
  • Formula:
  • C8H15NO4
  • Molecular Structure:
  • Synonyms:
  • Glycine,N-carboxy-, N-tert-butyl methyl ester (6CI);(tert-Butoxycarbonylamino)aceticacid methyl ester;BOC-glycine methyl ester;MethylN-[[(1,1-dimethylethyl)oxy]carbonyl]glycinate;N-(Carbo-tert-butyloxy)glycinemethyl ester;N-(tert-Butoxycarbonyl)glycine methyl ester;N-Boc-glycine methylester;
  • Molecular Weight:
  • 189.21
  • Density:
  • 1.072 g/cm3
  • Boiling Point:
  • 266.8 °C at 760 mmHg
  • Flash Point:
  • 115.2 °C
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CAS No. 

31954-27-5 Methyl N-(tert-butoxycarbonyl)glycinate

Appearance:White powder MF:C7H14ClNO2 MW:179.6446 MP:255~265℃
China (Mainland)   2912
  • Tel:0351-7436719
  • Address:Shuangta South Alley 46,2-1, YingZe Area,Taiyuan, ShanXi
MSN:zhuofang.2008@hotmail.com

CAS No. 

31954-27-5 Methyl N-(tert-butoxycarbonyl)glycinate

China (Mainland)   ISO  4490
  • Tel:+86-571-88938639
  • Address:B/2601 Fuli Building, 328# WenEr Rd. Hangzhou City 310012 China

CAS No. 

31954-27-5 Methyl N-(tert-butoxycarbonyl)glycinate

Assay:97%(min)  Appearance:Colorless to ye...
MF C8H15NO4 MW 189.21
China (Mainland)   3138
  • Tel:0086-21-37285021 0086-21-37285070
  • Address:NO.688 Qiu Shi Road,Shanghai Fine chemical Industrial Park, Jin Shan District, Shanghai 201512 ,China

CAS No. 

31954-27-5 Methyl N-(tert-butoxycarbonyl)glycinate

China (Mainland)   Manufacturer  2020
  • Tel:+86-519-88783621 88494669 88721665 8721667
  • Address:3# Hengluo Road, Henglin Town, Changzhou City, Jiangsu Province,China

CAS No. 

31954-27-5 Methyl N-(tert-butoxycarbonyl)glycinate

India   26
  • Tel:91 22 66382599

CAS No. 

31954-27-5 Methyl N-(tert-butoxycarbonyl)glycinate

Boc-glycine methyl ester
China (Mainland)   88
  • Tel:86-25-84513908
  • Address:nanjing taipingsouth road

CAS No. 

31954-27-5 Methyl N-(tert-butoxycarbonyl)glycinate

China (Mainland)   22
  • Tel:024-31818841
  • Address:shenyang

CAS No. 

31954-27-5 Methyl N-(tert-butoxycarbonyl)glycinate

India  
  • Tel:+91-22 22070099
  • Address:Suite 201, Maroo Bhavan, 51-55 Babu Genu Road, Mumbai 400002 (Hindusthan), India

CAS No. 

31954-27-5 Methyl N-(tert-butoxycarbonyl)glycinate

China (Mainland)  
  • Tel:+86-931-4562529 +86-931-4562565 +86-931-3111454
  • Address:Building 3,Northern District 5,Yantan Industrial Park, Lanzhou City, China PRC
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    Reference

    A simple, high-yielding synthesis of N-tert-butoxycarbonyl a-amino esters: precursors for a-amino aldehydes
    A simple, high-yielding synthesis of N-tert-butoxycarbonyl a-amino esters: precursors for a-amino aldehydes. McNulty, James; Still, Ian W. J. (J. Tuzo Wilson Res. Lab., Univ. Toronto, Mississauga, ON L5L 1C6, Can.). Synth.Several reagents with their cas registry numbers 2766-43-0 and 31954-27-5 are used here. Commun., 22(7), 979-85 (English) 1992. CODEN: SYNCAV. ISSN: 0039-7911. DOCUMENT TYPE: Journal CA Section: 34 (Amino Acids, Peptides, and Proteins) A general one-pot, two-stage procedure is described for the prepn. of the title compds. Boc-X-OMe (I; Boc = Me3CO2C; X = Phe, Pro, Tyr, Ser, Gly, DL-Trp) from the free amino acids in near quant. yields. Thus, Fischer esterification of the amino acid in dry acidic MeOH contg. mol. sieves gave the intermediate amino ester hydrochlorides, which were treated with Boc2O and excess Et3N in DMF to give I in 98-100% yields. I (R = Phe, Pro) were converted into the corresponding amino aldehydes Boc-X-H with DIBAL. .

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