CAS No.32231-06-4,Piperazine,1-(1,3-benzodioxol-5-ylmethyl)- Suppliers,MSDS download

Detail of "32231-06-4"

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CAS Number:

32231-06-4

Name:

Piperazine,1-(1,3-benzodioxol-5-ylmethyl)-

Superlist Name:

1-Piperonylpiperazine

Molecular Structure:

Formula:

C₁₂H₁₆N₂O₂

Molecular Weight:

220.27

Synonyms:

Piperazine,1-piperonyl- (7CI,8CI);1-(1,3-Benzodioxolan-5-ylmethyl)piperazine;1-(3,4-Methylenedioxybenzyl)piperazine;1-(4-Piperonyl)piperazine;1-(Benzo[1,3]dioxol-5-ylmethyl)piperazine;1-(Benzodioxol-5-ylmethyl)piperazine;1-[(2H-1,3-Benzodioxol-5-yl)methyl]piperazine;1-[(Benzo[d][1,3]dioxol-5-yl)methyl]piperazine;4-(4-Piperonyl)piperazine;4-[(Benzodioxol-5-yl)methyl]piperazine;5-(Piperazinomethyl)-1,3-benzodioxole;N-Piperonylpiperazine;N-[(1,3-Benzodioxol-5-yl)methyl]piperazine;1-(3,4-Methylenedioxyphenylmethyl)piperazine;

EINECS:

250-968-5

Density:

1.203 g/cm³

Melting Point:

36-40 °C(lit.)

Boiling Point:

330.5 °C at 760 mmHg

Flash Point:

158.4 °C

Appearance:

white to yellow or yellow-brownish cryst. solid

Hazard Symbols:

Risk Codes:

36/37/38

Safety:

26-37/39 Details

Reference

2,5-Disubstituted benzamides: 2,5-Disubstituted benzamides. Buzas, Andre; Lavielle, Gilbert (Universite d'Orleans, Fr.). Ger. Offen. DE 2705896 1 Sep 1977, 31 pp. (German). (Germany). CODEN: GWXXBX. CLASS: IC: C07C103-82.Several reagents such as 32231-06-4 is used here. PRIORITY: FR 76-5372 26 Feb 1976. DOCUMENT TYPE: Patent CA Section: 25 (Noncondensed Aromatic Compounds) Section cross-reference(s): 27, 28 Benzamides I [NRR1 = NHCH2CH2NEt2, (1-ethyl-2-pyrrolidinyl)methyl, piperidino, etc.; R2 = Me or alkyl; R3 = Me, Pr, Ph, 1-[(4-piperonyl-1-piperazinyl)methyl], etc.; X = O or NOH] were prepd. by treating the corresponding benzoyl chloride with HNRR1. Thus, 2-PrCO2C6H4CO2Me was prepd. from the hydroxybenzoate and rearranged over AlCl3 into 5,2-(PrCO)(HO)C6H3CO2Me, which was successively methylated, sapond., and chlorinated, and the benzoyl chloride was aminated with 2-(aminomethyl)-1-ethylpyrrolidine to give I [NRR1 = (1-ethyl-2-pyrrolidinyl)methyl, R2 = Me, R3 = Pr, X = O]. I showed antiemetic activity in tests with dogs.Some commonly used reagents like 32231-06-4 is used in this experiment. ..

2,5-Disubstituted benzamides: 2,5-Disubstituted benzamides. Buzas, Andre; Lavielle, Gilbert (Universite d'Orleans, Fr.). Ger. Offen. DE 2705896 1 Sep 1977, 31 pp. (German). (Germany). CODEN: GWXXBX. CLASS: IC: C07C103-82.Several reagents such as 32231-06-4 is used here. PRIORITY: FR 76-5372 26 Feb 1976. DOCUMENT TYPE: Patent CA Section: 25 (Noncondensed Aromatic Compounds) Section cross-reference(s): 27, 28 Benzamides I [NRR1 = NHCH2CH2NEt2, (1-ethyl-2-pyrrolidinyl)methyl, piperidino, etc.; R2 = Me or alkyl; R3 = Me, Pr, Ph, 1-[(4-piperonyl-1-piperazinyl)methyl], etc.; X = O or NOH] were prepd. by treating the corresponding benzoyl chloride with HNRR1. Thus, 2-PrCO2C6H4CO2Me was prepd. from the hydroxybenzoate and rearranged over AlCl3 into 5,2-(PrCO)(HO)C6H3CO2Me, which was successively methylated, sapond., and chlorinated, and the benzoyl chloride was aminated with 2-(aminomethyl)-1-ethylpyrrolidine to give I [NRR1 = (1-ethyl-2-pyrrolidinyl)methyl, R2 = Me, R3 = Pr, X = O]. I showed antiemetic activity in tests with dogs.Some commonly used reagents like 32231-06-4 is used in this experiment. ..

Detail of "32231-06-4"

Piperazine,1-(1,3-benzodioxol-5-ylmethyl)-

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Reference