Detail of "3230-69-1"

Reference

Chemiluminescence in liquid phase oxidation of intermediates in vitamin A and E production

Chemiluminescence in liquid phase oxidation of intermediates in vitamin A and E production. Pletneva, S. D.; Savin, N. A.; Bondareva, V. A. (Belgorod. Fil., Vses. Nauchno-Issled. Vitamin. Inst., Belgorod, USSR). Khim.-Farm. Zh., 18(8), 987-90 (Russian) 1984. CODEN: KHFZAN. ISSN: 0023-1134. DOCUMENT TYPE: Journal CA Section: 63 (Pharmaceuticals) Section cross-reference(s): 22 The chemiluminescence in liq. phase oxidn. of 3-methyl-2-penten-4-ynol [105-29-3], 3-methylpent-4-en-1-yn-3-ol (I) [3230-69-1], a b-aldehyde (II) [3155-71-3], pseudoionone (III) [141-10-6], 2,6,10-trimethyldodec-11-yn-10-ol (IV) [1604-35-9], 2,6,10,14-tetramethylhexadec-15-yn-14-ol (V) [29171-23-1], and 2,6,10-trimethylpentadeca-10,12-dien-14-one [1604-32-6] (intermediate in vitamin A [11103-57-4] and vitamin E [1406-18-4] manuf.) was investigated. The effect of antioxidants, ionol [128-37-0], hydroquinone [123-31-9], diaphen NN [93-46-9], and Neozone D [135-88-6] on chemiluminescence was also investigated. I has significant chemiluminescence properties and is oxidizable. Oxidn. and polymn. of III, IV and V at 90-140° showed that ionol, hydroquinone and diaphen NN did not inhibit the reactions.

Determination of self-association parameters of isomeric enynols from proton NMR data

Determination of self-association parameters of isomeric enynols from proton NMR data. Staroverov, V. M.; Shcherbakova, E. S.; Popovich, V. I.; Abramov, A. F.; Savina, N. V. (USSR). Zh. Prikl. Spektrosk., 45(2), 288-93 (Russian) 1986. CODEN: ZPSBAX. ISSN: 0514-7506. DOCUMENT TYPE: Journal CA Section: 22 (Physical Organic Chemistry) The thermodn. of self-assocn. of (E)- (I) and (Z)-HCYCCMe:CHCH2OH (II) and HCYCCMe(OH)CH:CH2 were studied in CCl4 as a function of concn. and temp. Thus, at 0.5 M, I exists as the monomer, dimer, tetramer, and hexamer, whereas II exists as the monomer, dimer, and hexamer with only a small amt. of tetramer. 6153-06-6 and 3230-69-1 are just another two chemicals used in this study. The anomalous chem. shift of hexamers may result from a cyclic structure. .