Detail of "3279-26-3"

Reference

Photoelectric spectra and electronic structure of organophosphorus compounds

Photoelectric spectra and electronic structure of organophosphorus compounds. I. Orbital model of the conformational isomerism of X2P-YCH3. Ermolaeva, L. V.; Zverev, V. V. (Inst. Org. Fiz. Khim. im. Arbuzova, Kazan, USSR). Zh. Strukt. Khim., 24(5), 37-43 (English) 1983. CODEN: ZSTKAI. ISSN: 0044-4634. DOCUMENT TYPE: Journal CA Section: 29 (Organometallic and Organometalloidal Compounds) Section cross-reference(s): 22 In the gas phase, R2POMe (R = H, halo) have the trans- and R2PSMe have the gauche-conformations. An orbital model was used to interpret the photoelec. spectra. The results from a theor.In this experiment, several chemicals are used like 14684-24-3 and 3279-26-3 anal. agree with calcns. by the CNDO/2 method. .

Reaction of dichloromethyl isocyanate with alkyl dihalo- and dialkyl halophosphites

Reaction of dichloromethyl isocyanate with alkyl dihalo- and dialkyl halophosphites. Shokol, V. A.; Kozhushko, B. N. (Inst. Org. Khim., Kiev, USSR). Zh. Obshch. Khim., 47(2), 321-8 (Russian) 1977. CODEN: ZOKHA4. DOCUMENT TYPE: Journal CA Section: 29 (Organometallic and Organometalloidal Compounds) Reaction of Cl2CHNCO with MeOPCl2 or BuOPF2 in the presence of FeCl3 gave 70% Cl2P(O)CHClNCO or 60% F2P(O)CHClNCO, resp. Similar reaction with (EtO)2PCl gave 45% (EtO)P(O)(CHClNCO)Cl. 37628-02-7 and 3279-26-3 which are cas registry numbers of substances are two of reagents here. Reaction of Cl2CHNCO with 1 mol of (EtO)2PF gave 27% (EtO)P(O)(CHClNCO)F and with 2 mols of (EtO)2PF, 30% [(EtO)P(O)F]2CHNCO. The reaction of these products with alcs. and amines were discussed. .