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CAS No.: | 33007-83-9 |
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Name: | TRIMETHYLOLPROPANE TRIS(3-MERCAPTOPROPIONATE) |
Article Data: | 6 |
Molecular Structure: | |
Formula: | C15H26 O6 S3 |
Molecular Weight: | 398.566 |
Synonyms: | Propanoicacid, 3-mercapto-, 2-ethyl-2-[(3-mercapto-1-oxopropoxy)methyl]-1,3-propanediylester (9CI); Propionic acid, 3-mercapto-, triester with2-ethyl-2-(hydroxymethyl)-1,3-propanediol (7CI,8CI); 1,3-Propanediol,2-ethyl-2-(hydroxymethyl)-, tris(3-mercaptopropionate) (8CI); 3TP6; MercaptateP 33; P 33; P 33 (ester); TMMP; TMTP; Thiocure TMPMP; Trimethylolpropanetris(3-mercaptopropionate); Trimethylolpropane tris(b-mercaptopropionate) |
EINECS: | 251-336-1 |
Density: | 1.212 g/cm3 |
Boiling Point: | 479.8 °C at 760 mmHg |
Flash Point: | 403.6 °C |
Solubility: | 320mg/L at 20℃ |
Hazard Symbols: | Xi |
Risk Codes: | 36/37/38 |
Safety: | 26-37/39 |
PSA: | 195.30000 |
LogP: | 1.97210 |
1,1,1-tri(hydroxymethyl)propane
3-mercaptopropionic acid
2-ethyl-2-((3-mercaptopropanoyloxy)methyl)propane-1,3-diyl bis(3-mercaptopropanoate)
Conditions | Yield |
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With sulfuric acid In toluene at 130℃; for 4h; Dean-Stark; | 92% |
With SO42-/ Al2O3-ZrO2 at 80 - 100℃; | 199.1 g |
In toluene at 120℃; for 24h; Dean-Stark; | |
With p-toluenesulfonylanhydride In toluene at 90 - 130℃; for 5h; | 398 g |
2-ethyl-2-((3-mercaptopropanoyloxy)methyl)propane-1,3-diyl bis(3-mercaptopropanoate)
(E)-1-(4-(allyloxy)phenyl)ethan-1-one oxime
Conditions | Yield |
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With 2,2-dimethoxy-2-phenylacetophenone In tetrahydrofuran at 20℃; for 1h; Inert atmosphere; UV-irradiation; | 100% |
2-ethyl-2-((3-mercaptopropanoyloxy)methyl)propane-1,3-diyl bis(3-mercaptopropanoate)
Conditions | Yield |
---|---|
With DBN In chloroform at 20℃; for 0.5h; Michael Addition; | 98% |
2-ethyl-2-((3-mercaptopropanoyloxy)methyl)propane-1,3-diyl bis(3-mercaptopropanoate)
C54H68O12S15
Conditions | Yield |
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In dichloromethane Inert atmosphere; | 93% |
2-ethyl-2-((3-mercaptopropanoyloxy)methyl)propane-1,3-diyl bis(3-mercaptopropanoate)
2-Isocyanatoethyl methacrylate
C36H53N3O15S3
Conditions | Yield |
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With dibutyltin dilaurate In toluene at 28℃; for 6.5h; | 81% |
2-ethyl-2-((3-mercaptopropanoyloxy)methyl)propane-1,3-diyl bis(3-mercaptopropanoate)
4-(diphenylamino)benzaldehyde N-2,3-epoxypropyl-N-phenylhydrazone
Conditions | Yield |
---|---|
triethylamine In tetrahydrofuran for 12h; Heating / reflux; | 71% |
2-ethyl-2-((3-mercaptopropanoyloxy)methyl)propane-1,3-diyl bis(3-mercaptopropanoate)
Conditions | Yield |
---|---|
With 1,8-diazabicyclo[5.4.0]undec-7-ene In dichloromethane at -78℃; for 1.41667h; Reagent/catalyst; Solvent; Concentration; Temperature; Inert atmosphere; | 55% |
2-ethyl-2-((3-mercaptopropanoyloxy)methyl)propane-1,3-diyl bis(3-mercaptopropanoate)
Conditions | Yield |
---|---|
With 1,8-diazabicyclo[5.4.0]undec-7-ene at 20℃; for 384h; Michael Addition; | 35% |
2-ethyl-2-((3-mercaptopropanoyloxy)methyl)propane-1,3-diyl bis(3-mercaptopropanoate)
acrylic acid
Desyl chloride
Conditions | Yield |
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Stage #1: 2-ethyl-2-((3-mercaptopropanoyloxy)methyl)propane-1,3-diyl bis(3-mercaptopropanoate) With triethylamine In acetonitrile at 20℃; Stage #2: acrylic acid In acetonitrile at 25℃; for 3h; Stage #3: Desyl chloride In acetonitrile at 25℃; for 2h; | 11% |
2-ethyl-2-((3-mercaptopropanoyloxy)methyl)propane-1,3-diyl bis(3-mercaptopropanoate)
pentaerythritol triallyl ether
Conditions | Yield |
---|---|
With 1,1-bis(tert-butylperoxy)-3,3,5-trimethylcyclohexane Heating; |