Detail of "3316-24-3"

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CAS Number:
3316-24-3
Name:
Benzene,1-methoxy-2-(2-nitroethenyl)-
Superlist Name:
1-(2-Methoxyphenyl)-2-nitroethene
Molecular Structure:
Formula:
C9H9 N O3
Molecular Weight:
179.19
Synonyms:
Anisole,o-(2-nitrovinyl)- (7CI,8CI); 2-(2-Nitrovinyl)anisole; 2-Methoxy-b-nitrostyrene; NSC 170699; NSC59450; o-Methoxy-b-nitrostyrene
Density:
1.189 g/cm³
Melting Point:
46-50 ºC
Boiling Point:
299.8 °C at 760 mmHg
Flash Point:
141.7 °C
Hazard Symbols:
Risk Codes:
R22;R36/37/38
Safety:
Moderately toxic by ingestion. When heated to decomposition it emits toxic vapors of NO_x. Details

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Addition of some active methylene compounds to: Addition of some active methylene compounds to .beta.-nitrostyrenes. Ali, Mohamed I.; Abou-State, M. Amine; Hassan, N. M.; El-Behairy, M.Some commonly used reagents like 62384-51-4 and 3316-24-3 are used in this experiment. A. (Fac. Sci., Univ. Cairo, Cairo, Egypt). Egypt. J. Chem., Volume Date 1975, 18(1), 55-61 (English) 1976. CODEN: EGJCA3. DOCUMENT TYPE: Journal CA Section: 25 (Noncondensed Aromatic Compounds) Section cross-reference(s): 26, 27 Michael addn. of MeCOCH2CONHR (R = Ph, substituted phenyl, PhCH2, cyclohexyl, 1-naphthyl) with R1CH:CHNO2 (R1 = Ph, 2-naphthyl, 2-thienyl) gave ten MeCOCH(CHR1CH2NO2)CONHR, and of PhCOCH2CONHR2 (R2 = Ph, substituted phenyl) with R3CH:CHNO2 (R3 = Ph, substituted phenyl, 2-naphthyl, 2-thienyl) gave nine PhCOCH(CHR3CH2NO2)CONHR2. Similarly PhCOCH2CO2Et or PhSO2CH2CONHPh with nitrostyrenes gave the corresponding adducts. EtONa or Et3N was used as a catalyst for the addn. reaction. .