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Novel isatin-Schiff base Cu(II) and Ni(II) complexes

All Rights Reserved. Novel isatin-Schiff base Cu(II) and Ni(II) complexes. X-ray crystal structure of bis[3-(4-hexylphenylimino)-1H-indol-2(3H)-one]-dichlorocopper(II) complex.In this study，33228-45-4 is also used. Ercag, Ayse; Yildirim, Sema Ozturk; Akkurt, Mehmet; Ozgur, Mahmure Ustun; Heinemann, Frank W. (Engineering Faculty, Chemistry Department, Istanbul University, Istanbul 34320, Turk.). Chinese Chemical Letters, 17(2), 243-246 (English) 2006 Chinese Chemical Society. CODEN: CCLEE7. ISSN: 1001-8417. DOCUMENT TYPE: Journal CA Section: 78 (Inorganic Chemicals and Reactions) Section cross-reference(s): 75, 76 The Schiff base ligand (HL) derived from 4-hexylaniline with isatin (1H-indole-2,3-dione), 3-(4-hexylphenylimino)-1H-indol-2(3H)-one, and its complexes with Cu(II and Ni(II) were prepd. and characterized by anal., spectroscopic (IR, UV-visible, Mass) techniques, elec. cond., magnetic and thermal measurements. The crystal and mol. structure of [Cu(HL)2Cl2] was detd. by a single-crystal x-ray diffraction study. The mol. structure of the title compd. has an inversion center on the Cu atom. .