Detail of "3357-16-2"
- CAS Number:
- 3357-16-2
- Name:
5,5-Dimethyl-3-pyrrolidino-cyclohex-2-en-1-one
- Molecular Structure:
- Formula:
- C12H19NO
5,5-Dimethyl-3-pyrrolidino-cyclohex-2-en-1-one
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Reference
- Effect of nitrogen substituents on carbon-nitrogen rotational barriers in enamine derivatives
- Effect of nitrogen substituents on carbon-nitrogen rotational barriers in enamine derivatives. Azzaro, Marcel; Geribaldi, Serge; Videau, Bruno (Lab. Chim.Except for chemicals metioned above, 3357-16-2 is also used. Phys. Org., Univ. Nice, Nice 06034, Fr.). Magn. Reson. Chem., 23(1), 28-32 (English) 1985. CODEN: MRCHEG. ISSN: 0749-1581. 3357-16-2 which is the cas registry number of some chemical is mentioned. DOCUMENT TYPE: Journal CA Section: 22 (Physical Organic Chemistry) Rates of rotation around the C-N bond in a series of ten N,N-disubstituted 3-amino-5,5-dimethylcyclohex-2-enones were detd. from total NMR line shape anal. Linear correlations exist between DG2981 and parameters describing the inductive and steric effects of N-alkyl substituents. The substituent effects on the barriers seem to occur mainly through a change in the potential energy of non-bonded interactions between the N substituents and the H atoms in the ortho position to the amino group. ..
- Effect of nitrogen substituents on carbon-nitrogen rotational barriers in enamine derivatives
- Effect of nitrogen substituents on carbon-nitrogen rotational barriers in enamine derivatives. Azzaro, Marcel; Geribaldi, Serge; Videau, Bruno (Lab. Chim.Except for chemicals metioned above, 3357-16-2 is also used. Phys. Org., Univ. Nice, Nice 06034, Fr.). Magn. Reson. Chem., 23(1), 28-32 (English) 1985. CODEN: MRCHEG. ISSN: 0749-1581. 3357-16-2 which is the cas registry number of some chemical is mentioned. DOCUMENT TYPE: Journal CA Section: 22 (Physical Organic Chemistry) Rates of rotation around the C-N bond in a series of ten N,N-disubstituted 3-amino-5,5-dimethylcyclohex-2-enones were detd. from total NMR line shape anal. Linear correlations exist between DG2981 and parameters describing the inductive and steric effects of N-alkyl substituents. The substituent effects on the barriers seem to occur mainly through a change in the potential energy of non-bonded interactions between the N substituents and the H atoms in the ortho position to the amino group. ..