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CAS No.: | 34010-21-4 |
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Name: | (Z)-11-HEXADECEN-1-YL ACETATE |
Article Data: | 31 |
Molecular Structure: | |
Formula: | C18H34 O2 |
Molecular Weight: | 282.467 |
Synonyms: | 11-Hexadecen-1-ol,acetate, (11Z)- (9CI); 11-Hexadecen-1-ol, acetate, (Z)- (8CI);(Z)-11-Hexadecen-1-ol acetate; (Z)-11-Hexadecen-1-yl acetate;(Z)-11-Hexadecenyl acetate; 1-Acetoxy-(Z)-11-hexadecene; Z11-16:Ac;cis-11-Hexadecen-1-ol acetate; cis-11-Hexadecen-1-yl acetate;cis-11-Hexadecenyl acetate |
Density: | 0.875g/cm3 |
Boiling Point: | 348.7°Cat760mmHg |
Flash Point: | 88.4°C |
PSA: | 26.30000 |
LogP: | 5.80680 |
Conditions | Yield |
---|---|
With pyridine In benzene for 4h; Heating; | 98.5% |
Conditions | Yield |
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With pyridine for 12h; Ambient temperature; | 98% |
With pyridine at 0℃; for 3h; | 97% |
With triethylamine In dichloromethane at 20℃; for 8h; Inert atmosphere; Schlenk technique; Cooling with ice; | 94% |
Conditions | Yield |
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With pyridine In dichloromethane at 20℃; | 90% |
(Z)-2-(hexadec-11-en-1-yloxy)tetrahydro-2H-pyran
acetyl chloride
(Z)-11-hexadecen-1-yl acetate
Conditions | Yield |
---|---|
In acetic acid at 35 - 40℃; | 68% |
In hexane; acetic acid |
1-acetoxy-7-bromoheptane
(Z)-4-nonenyl bromide
(Z)-11-hexadecen-1-yl acetate
Conditions | Yield |
---|---|
(i) Mg, (ii) /BRN= 1760288/; Multistep reaction; |
(11Z)-hexadeca-1,11-diene
(Z)-11-hexadecen-1-yl acetate
Conditions | Yield |
---|---|
Yield given. Multistep reaction; | |
Multi-step reaction with 2 steps 1: 1. 9-BBN, 2. 3N NaOH, 26percent H2O2 / 1. THF, r.t., 5 h, 2. r.t., 17 h 2: 98 percent / pyridine / 12 h / Ambient temperature View Scheme | |
Multi-step reaction with 2 steps 1: 9-BBN / tetrahydrofuran 2: Py / 3 h / Heating View Scheme |
Hexadec-11-ynyl acetate
(Z)-11-hexadecen-1-yl acetate
Conditions | Yield |
---|---|
With methanol; 9-borabicyclo[3.3.1]nonane dimer; acetic acid 1.) THF, 0 deg C, 48 h, 2.) 25 deg C, 1 h; Yield given. Multistep reaction; | |
With hydrogen; P-2 Ni Yield given; |
n-butyl magnesium bromide
acetic anhydride
(Z)-2-(8-phenylthiododec-11-enyloxy)tetrahydro-2H-pyran
A
(Z)-11-hexadecen-1-yl acetate
B
(E)-11-hexadecen-1-yl acetate
Conditions | Yield |
---|---|
1,2-bis(diphenylphosphino)ethane nickel(II) chloride 1.) ether, 12 h, room temp., 2.) 80 deg C, 15 h; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts; |
11-hexadecene-1-ol
acetic anhydride
A
(Z)-11-hexadecen-1-yl acetate
B
(E)-11-hexadecen-1-yl acetate
Conditions | Yield |
---|---|
With pyridine Yield given. Yields of byproduct given. Title compound not separated from byproducts; |
11-hexadecyn-1-ol
(Z)-11-hexadecen-1-yl acetate
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: H2 / Pd/BaSO4 2: pyridine View Scheme | |
Multi-step reaction with 2 steps 1: 92 percent / i-BuMgBr, Cp2TiCl2 2: 90 percent / pyridine View Scheme | |
Multi-step reaction with 2 steps 1: 1.) isobutylmagnesium bromide; 2.) C5H5TiCl2 / 1.) diethyl ether, 0 deg C, 15 min; 2.) room temp., 1-1,5 h 2: 90 percent / pyridine View Scheme |