CAS No.3587-60-8,Benzene,[(chloromethoxy)methyl]- Suppliers

Detail of "3587-60-8"

CAS Number:

3587-60-8

Name:

Benzene,[(chloromethoxy)methyl]-

Superlist Name:

Benzylchloromethyl ether

Molecular Structure:

Formula:

C₈H₉ClO

Molecular Weight:

156.61

Synonyms:

Ether,benzyl chloromethyl (6CI,7CI,8CI);Benzyloxymethylchloride;Chloromethyl benzyl ether;Chloromethyl phenylmethyl ether;

Density:

1.118 g/cm³

Boiling Point:

207.1 °C at 760 mmHg

Flash Point:

91.1 °C

Appearance:

Colorless liquid

Hazard Symbols:

Risk Codes:

45-22-23-37/38-41-48/22-36/37/38-20/21/22

Safety:

53-26-39-45-36/37/39-36 Details

Transport Information:

UN 2810 6.1/PG 3

Reference

Preparation of decahydro-2H-benzo[a]xanthene-3,11-diol derivatives as kampanol analogs and their intermediate: Several substances are used for example 6751-75-3 and 3587-60-8 which are their cas registry numbers. Preparation of decahydro-2H-benzo[a]xanthene-3,11-diol derivatives as kampanol analogs and their intermediate. Kato, Tadashi; Inoue, Munenobu; Nakaya, Mari (Sagami Chemical Research Center, Japan). Jpn. Kokai Tokkyo Koho JP 2004035497 A2 5 Feb 2004, 20 pp. (Japanese). (Japan). CODEN: JKXXAF. CLASS: ICM: C07D311-78. ICS: C07F007-18. APPLICATION: JP 2002-196384 4 Jul 2002. DOCUMENT TYPE: Patent CA Section: 30 (Terpenes and Terpenoids) Section cross-reference(s): 1 Title derivs. I (R1, R2 = H, protecting group), which may be useful as protein farnesyl transferase and antitumor agents (no data) are prepd. via hydronaphthalenes II (R1-R3 = H, protecting group; R4 = R5 = H or R4R5 = O) from (protected) 5,5,8a-trimethyl-1-methylene-6-hydroxyoctahydronaphthalen-2-one and (protected) 2-bromoresorcinol. Thus, coupling of 2-benzyloxymethoxy-6-methoxymethoxybromobenzene with (4aR,6S,8aS)-6b-(tert-butyldimethylsiloxy)-5,5,8ab-trimethyl-1-methylen e-3,4,4 aa-5,6,7,8,8a-octahydronaphthalen-2-one by Grignard reaction gave 95% (4aR,6S,8R,8aS)-1b-II (R1 = b-tert-butyldimethylsiloxy, R2 = MeOCH2, R3 = PhCH2OCH2, R4R5 = O), which was treated with methyltriphenylphosphonium bromide, refluxed with Li and NH3, treated with N-(phenylseleno)phthalimide, and deprotected to afford (3S,4aR,6aS,12aR,12bS)-I (R1 = R2 = H). .

Detail of "3587-60-8"

Benzene,[(chloromethoxy)methyl]-

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Reference