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3590-84-9

Basic Information
CAS No.: 3590-84-9
Name: Tetraoctyltin
Article Data: 28
Molecular Structure:
Molecular Structure of 3590-84-9 (Tetraoctyltin)
Formula: C32H68 Sn
Molecular Weight: 571.602
Synonyms: Tin,tetraoctyl- (6CI,7CI); NSC 65527; Tetra-n-octylstannane; Tetra-n-octyltin;Tetraoctylstannane; Tetraoctyltin
EINECS: 222-733-7
Density: 0,98 g/cm3
Boiling Point: 549.4 ºCat 760 mmHg
Flash Point: 282 ºC
Risk Codes: 36/37
Safety: Low toxicity by parenteral route. When heated to decomposition it emits toxic vapors of Sn.
PSA: 0.00000
LogP: 12.87720
Synthetic route
111-85-3

1-Chlorooctane

7646-78-8

tin(IV) chloride

3590-84-9

tetraoctyltin

Conditions
ConditionsYield
With magnesium In diethyl ether; toluene at 50 - 65℃; Solvent; Inert atmosphere; Flow reactor;98.5%
With sodium In Petroleum ether 13 h;65-80
With Na In petroleum ether 13 h;65-80
111-85-3

1-Chlorooctane

3542-36-7

di-n-octyltin dichloride

3590-84-9

tetraoctyltin

Conditions
ConditionsYield
With Na98%
With sodium98%
7646-78-8

tin(IV) chloride

1070-00-4

trioctylaluminum

3590-84-9

tetraoctyltin

Conditions
ConditionsYield
In dibutyl ether 70°C;98%
In dibutyl ether 70°C;98%
In dibutyl ether 70°C;98%
7646-78-8

tin(IV) chloride

24219-37-2

di-n-octylmagnesium

3590-84-9

tetraoctyltin

Conditions
ConditionsYield
In tetrahydrofuran; n-heptane a soln. of SnCl4 (18 mmol) in heptane was added dropwise within 10 min to a soln. of (C8H17)2Mg (44 mmol) in THF with stirring (pptn.); the mixt. was refluxed for 3 1/3 h, then treated with H2O and 10% HCl;; the org. layer was separated and dried with CaCl2, the solvents were distilled off in vac., the residue was istilled in high vac.; 99.1% purity (asdetermined by gas chromy.); identified by mass spectrometry; elem. anal.;;95%
17049-49-9

octylmagnesium bromide

7646-78-8

tin(IV) chloride

3590-84-9

tetraoctyltin

Conditions
ConditionsYield
In toluene90%
In n-heptane87.93%
In n-heptane87.93%
In diethyl ether 130-140°C, 10 h;59%
2787-93-1

bis(trioctylstannyl) oxide

A

3590-84-9

tetraoctyltin

B

21227-24-7

hexaoctyldistannane

Conditions
ConditionsYield
With magnesium In tetrahydrofuran a soln. of ditin oxide in dry THF was added dropwise to a suspn. of a magnesium powder, activated by BrCH2CH2Br or I2, in dry THF, mixt. was heated at reflux for 15 h; petroleum ether was added, filtered, solvents evapd., residue was distilled;A 0%
B 82%
With sodium In neat (no solvent) stoich. amt. of sodium (2 mol for 1 mol of ditin oxide), 120°C, 48 h; unreacted n-Oct6Sn2O was removed by filtration in pentane through a short SiO2 column, n-Oct4Sn was removed by distn.;A 1-5
B 68%
7646-78-8

tin(IV) chloride

38841-98-4

n-octylmagnesium chloride

3590-84-9

tetraoctyltin

Conditions
ConditionsYield
64.9%
64.9%
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Chemistry

IUPAC Name: Tetraoctylstannane
The MF of Tetraoctyltin (CAS NO.3590-84-9) is C32H68Sn.

                   
The MW of Tetraoctyltin (CAS NO.3590-84-9) is 571.59.
Synonyms of Tetraoctyltin (CAS NO.3590-84-9): stannane, tetraoctyl- ; Tetra-n-octylstannane ; Tetra-n-octyltin ; Tetraoctylstannan
Refraction Index: 1.4677
EINECS: 222-733-7
Flash Point: 282 °C
Boiling Point: 549.4 °C
Density: 0,98 g/ml

Uses

 Tetraoctyltin (CAS NO.3590-84-9) is mainly used in the production of PVC heat stabilizers.

Toxicity Data With Reference

1.    

par-mus LDLo:34 g/kg

    COREAF    Comptes Rendus Hebdomadaires des Seances de l’Academie des Sciences. 239 (1954),1091.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Low toxicity by parenteral route. When heated to decomposition it emits toxic vapors of Sn.Safety information of Tetraoctyltin (CAS NO.3590-84-9):
Risk Statements 
36/37 Irritating to eyes and respiratory system
Safety Statements 
24 Avoid contact with skin
TSCA  Yes