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Detail of "35999-20-3"

  • CAS Number:
  • 35999-20-3
  • Name:

  • 3-Chloro-1-(4-methoxyphenyl)propan-1-one

  • Molecular Structure:
  • Formula:
  • C10H11ClO2
  • Molecular Weight:
  • 198.65
  • Synonyms:
  • 2-Chloro-4'-Methoxypropiophenone;4'-Methoxy-3-chloropropiophenone;beta-Chloro-4-methoxypropiophenone;
  • Density:
  • 1.149 g/cm3
  • Boiling Point:
  • 330 °C at 760 mmHg
  • Flash Point:
  • 143.7 °C
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CAS No.35999-20-3 3-Chloro-1-(4-methoxyphenyl)propan-1-one

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Reference

Photodegradable polymers
Photodegradable polymers. Lukac, Ivan; Hrdlovic, Pavol; Manasek, Zdenek (Czech. ). Czech. CS 170397 15 Jul 1977,4 pp. (Czech). (Czechoslovakia). CODEN: CZXXA9. CLASS: IC: C08F212-08. APPLICATION: CS 73-7728 12 Nov 1973. DOCUMENT TYPE: Patent CA Section: 36 (Plastics Manufacture and Processing) Homopolymers of CH2:CHCOC6H4OR-p (R = C1-8 alkyl) (I) or I copolymers with vinyl monomers (e.g., Me methacrylate or styrene) (I-vinyl monomer mol. ratio 1:(0.5-40)] were prepd. Thus, 238 g b-chloro-p-methoxypropiophenone [35999-20-3] and 163.2 g NaOAc were dissolved in 1500 mL EtOH and the soln. refluxed 30 min to give p-methoxyacrylophenone (I) [7448-86-4] in 81% yield. Me methacrylate 88, I 12, and AIBN 0.05 wt.% were polymd. 72 h in the absence of light at 25° to give, after pptn. with MeOH, 19% yield of copolymer (II) [53640-69-0]. II films of 0.03-mL thickness on exposure to UV light in an oxidizing atm. at 60° for 50 h became browned and brittle as compared with a control which was not degraded.
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