Detail of > 36042-94-1
- CAS Number:
- 36042-94-1
- Name:
Phosphinous chloride,P,P-bis(2-methylphenyl)-
- Superlist Name:
- Chlorodi(o-tolyl)phosphine
- Formula:
- C14H14ClP
- Molecular Structure:

- Synonyms:
- Phosphinouschloride, bis(2-methylphenyl)- (9CI);Bis(2-methylphenyl)chlorophosphine;Bis(2-methylphenyl)phosphinous chloride;Bis(2-tolyl)phosphinous chloride;Bis(o-methylphenyl)phosphine chloride;Chlorobis(2-methylphenyl)phosphine;Chlorobis(o-tolyl)phosphine;Chlorodi-o-tolylphosphine;Di(o-methylphenyl)phosphine chloride;Di-o-tolylchlorophosphine;Di-(o-tolyl)phosphinchlorid;
- Molecular Weight:
- 248.69
- Melting Point:
- 57 °C
- Boiling Point:
- 357.3 °C at 760 mmHg
- Flash Point:
- 169.9 °C
- Hazard Symbols:
F,
C- Risk Codes:
- 17-34
- Safety:
- 26-36/37/39-45Details
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Reference
- Synthesis of some o-substituted diarylchlorophosphines
- Synthesis of some o-substituted diarylchlorophosphines. Shvets, A. A.; Moiseeva, O. A.; Osipov, O. A. 36042-94-1 which is the cas registry number is also used here. (Rostov-on-Don Gos. Univ., Rostov-on-Don, USSR). Zh. Obshch. Khim., 48(1), 232-3 (Russian) 1978. CODEN: ZOKHA4. ISSN: 0044-460X. DOCUMENT TYPE: Journal CA Section: 29 (Organometallic and Organometalloidal Compounds) (O-MeC6H4)2PCl, prepd. by the Grignard reaction of o-MeC6H4Br with PCl3, was treated with BuOH in Et3N at -5° to give 52% (o-MeC6H4)2POBu, which with BrCH2COC6H4NO2-p at 110° gave 63% (o-MeC6H4)2P(O)CH2COC6H4NO2-p. .
- SimplePHOX, a readily available chiral ligand system for iridium-catalyzed asymmetric hydrogenation
- SimplePHOX, a readily available chiral ligand system for iridium-catalyzed asymmetric hydrogenation. [Erratum to document cited in CA].Several substances are used for example 36042-94-1 which is its cas registry number. Smidt, Sebastian P.; Menges, Frederik; Pfaltz, Andreas (Department of Chemistry, University of Basel, Basel CH-4056, Switz.). Organic Letters, 6(20), 3653 (English) 2004 American Chemical Society. CODEN: ORLEF7. ISSN: 1523-7060. DOCUMENT TYPE: Journal CA Section: 25 (Benzene, Its Derivatives, and Condensed Benzenoid Compounds) On page 2024, Table 1, entries 13-18, the abs. configuration of the hydrogenation products is (S), not (R), in the last column. 36042-94-1 is the cas registry number. This chemical is also mentioned in this article. ..
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