Detail of "36319-88-7"
- CAS Number:
- 36319-88-7
- Name:
2,4-Cyclopentadien-1-one,2,5-bis(1,1-dimethylethyl)-
- Molecular Structure:
- Formula:
- C13H20 O
- Synonyms:
- 2,5-Di-tert-butyl-2,4-cyclopentadien-1-one;2,5-Di-tert-butylcyclopentadienone
2,4-Cyclopentadien-1-one,2,5-bis(1,1-dimethylethyl)-
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Reference
- Photochemical decomposition of cyclohexadienone peroxides
- Photochemical decomposition of cyclohexadienone peroxides. Lind, H.; Winkler, T.; Loeliger, H. (Div. Kunstst. Addit., Ciba-Geigy A.-G., Basel, Switz.). J. Polym. Sci., Polym. Symp., Volume Date 1976, 57(Degradation Stab. Polyolefins), 225-8 (English) 1977. CODEN: JPYCAQ. DOCUMENT TYPE: Journal CA Section: 36 (Plastics Manufacture and Processing) Section cross-reference(s): 24 Photolysis of 2,6-di-tert-butyl-4-(tert-butylperoxy)-4-methyl-2,5-cyclohexadienone (I) [13154-57-9] in C6H6 (7.5 ′ 10-3M) under N gave 2,5-di-tert-butyl-2,4-cyclopentadienone [36319-88-7] 3, 3-acetyl-2,5-di-tert-butyl-2,4-cyclopentadienone [61756-39-6] 14, 4-acetyl-2,5-di-tert-butyl-2-cyclopentenone [61207-20-3] 12, 4-acetyl-5-butoxy-2,5-di-tert-butyl-2-cyclopentenone [64844-81-1] 12, 5-acetyl-1,3-di-tert-butyl-bicyclo[2.1.0]pentan-2-one [64821-72-3] 21, and 3-tert-butyl-4-(3,3-dimethyl-1-butenyl)-5-methyl-2-(5H)-furanone [64821-73-4] 10%. Photolysis of I in MeOH gave an 80% yield of 3a,5-di-tert-butyl-3,3a,4,6a-tetrahydro-1-hydroxy-1-methyl-1H-cyclopent a[c]furan-4-one [64821-74-5]. Possible mechanisms were proposed.
- Photochemistry of cyclohexadienone peroxides: structure of the intermediate radical
- Photochemistry of cyclohexadienone peroxides: structure of the intermediate radical. Lind, H.; Loeliger, H. (Plast. Addit. Div.Some commonly used reagents like 110-05-4 and 36319-88-7 are used in this experiment., Ciba-Geigy Ltd., Basel, Switz.). Tetrahedron Lett., (29), 2569-70 (English) 1976. CODEN: TELEAY. DOCUMENT TYPE: Journal CA Section: 22 (Physical Organic Chemistry) Photolysis in the ESR cavity of a soln. of 2,5-tert-butyl-2,4-cyclopentadien-1-one in Me3COOCMe3 and MeCHO gave a spectrum of 2,5-di-tert-butyl-4-acetyl-2-cyclopenten-1-one (I) thus confirming the structure of the intermediate radical in the photodecompn. of 4-tert-butylperoxy-4-methyl-2,6-di-tetrt-butyl-2,5-cyclohexadien-1-one (Lind, H., et al., 1976). .