Detail of "36756-79-3"

CAS Number:
36756-79-3
Name:
Carbamothioic acid,N,N-bis(1-methylpropyl)-, S-(phenylmethyl) ester
Molecular Structure:
Formula:
C16H25 N O S
Molecular Weight:
279.48
Synonyms:
Carbamothioicacid, bis(1-methylpropyl)-, S-(phenylmethyl) ester (9CI); Drepamon; M 3432; S-Benzyldi-sec-butylthiocarbamate; Thiocarbazil; Tiocarbazil
Density:
1.022g/cm³
Boiling Point:
372.5°Cat760mmHg
Flash Point:
179.1°C
Hazard Symbols:
Moderately toxic by skin contact. Low toxicity by ingestion.
Safety:
Moderately toxic by skin contact. Low toxicity by ingestion. When heated to decomposition it emits toxic vapors of NO_x and SO_x. Details

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Tiocarbazil

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Efficacy of herbicides in direct sown short duration rice: Efficacy of herbicides in direct sown short duration rice. Subbiah, K. K.; Morachan, Y. B. (Tamil Nadu Agric. Univ., Coimbatore, India). Madras Agric. J., 63(4), 242-3 (English) 1976. CODEN: MAAJAP. DOCUMENT TYPE: Journal CA Section: 5 (Agrochemicals) Of 11 herbicides, applied postplant singly and in binary mixts. to rice, into which Echinochloa and Cyperus were sown, C 19490-2,4-D IPE mixt. [50933-14-7] (0.75 and 0.5 kg/ha, resp.), 1.0 kg Avirosan [12701-69-8], and 2.0 kg M 3432 [36756-79-3]/ha, most effectively controlled the above weeds and Marsilea, and gave the highest rice yields.

Photochemistry and volatility of Drepamon in water: Photochemistry and volatility of Drepamon in water. Draper, William M.; Crosby, Donald G. (Dep. Environ. Toxicol., Univ. California, Davis, CA 95616, USA). J. Agric. Food Chem., 32(4), 728-33 (English) 1984. CODEN: JAFCAU. ISSN: 0021-8561. DOCUMENT TYPE: Journal CA Section: 5 (Agrochemical Bioregulators) The aquatic environmental chem. of the herbicide Drepamon (I) [36756-79-3] was investigated in lab. studies of photochem. reactivity and volatilization. In distd. water I photooxidized slowly to N-[(benzylsulfinyl)carbonyl]-N,N-di-sec-butylamine (I sulfoxide) [51955-39-6], an intermediate that underwent further direct photochem. There are some commonly used reagents like 10156-71-5 in this article. conversion to benzaldehyde [100-52-7]. Traces of H2O2 greatly accelerated the photodecompn. of I and altered the distribution of photoproducts so that phenols predominated. Preoxide-initiated free radical photooxidn. included S oxidn. and N-dealkylation as well. I, its phenolic products, benzaldehyde, and sec-butylamine [13952-84-6] were analyzed by gas-liq. chromatog. The thermally-unstable sulfoxide and sulfone were detd. by HPLC. I volatilized from aq. solns. more rapidly than the structurally related herbicides molinate [2212-67-1] and thiobencarb [28249-77-6]. .