Detail of "3730-60-7"

CAS Number:
3730-60-7
Name:
2-Hexanol,2,5-dimethyl-
Molecular Structure:
Formula:
C₈H₁₈O
Molecular Weight:
130.23
Synonyms:
2,5-Dimethyl-2-hexanol;NSC 5594;2-Hexanol, 2,5-dimethyl-, (S)-;2,5-dimethyl-hexan-2-ol;Dimethyl isoamyl carbinol;
EINECS:
223-085-8
Density:
0.821 g/cm³
Boiling Point:
157.9 °C at 760 mmHg
Flash Point:
56.6 °C
Risk Codes:
10
Safety:
23-36/37/39 Details
Transport Information:
1987

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Chemistry of dioxiranes: Chemistry of dioxiranes. 32. Dimethyldioxirane reactions: rate acceleration due to intramolecular H-bonding. Murray, Robert W.; Gu, Hong (Dep. Chem., Univ. Missouri-St. Louis, St. Louis, MO 63121, USA). Journal of Physical Organic Chemistry, 9(11), 751-758 (English) 1996 Wiley.Several reagents such as 591-76-4 is used here. CODEN: JPOCEE. ISSN: 0894-3230. DOCUMENT TYPE: Journal CA Section: 22 (Physical Organic Chemistry) Abs. rate studies were carried out on a series of C-H insertion reactions of dimethyldioxirane (1). The substrates were chosen so that the distance between a single tertiary C-H bond and an OH group could be varied. The measured rate consts. indicate that a rate acceleration occurs when the distance between the reacting C-H bond and the OH group permits intramol. H-bonding stabilization of the transition state. A similar study in related compds. without the OH group showed no effect of chain length on the rate of the C-H insertion reaction. A related study of the epoxidn. reaction of 1 also found an increased rate when chain length permitted intramol. H-bonding by an OH group. .