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| CAS No.: | 392-56-3 |
|---|---|
| Name: | HEXAFLUOROBENZENE |
| Article Data: | 84 |
| Molecular Structure: | |
|
|
|
| Formula: | C6F6 |
| Molecular Weight: | 186.056 |
| Synonyms: | Benzene,hexafluoro- (6CI,8CI,9CI);Hexafluorobenzene; |
| EINECS: | 206-876-2 |
| Density: | 1.622 g/cm3 |
| Melting Point: | 3.7-4.1 °C(lit.) |
| Boiling Point: | 80.5 °C at 760 mmHg |
| Flash Point: | 10 °C |
| Solubility: | Immiscible with water. |
| Appearance: | colourless liquid |
| Hazard Symbols: |
 F,  Xi
|
| Risk Codes: | 11-36/37/38 |
| Safety: | 16-33-7/9-29-26-37/39 |
| Transport Information: | UN 1993 3/PG 2 |
| PSA: | 0.00000 |
| LogP: | 2.52120 |
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Chemistry
Chemical Name: Hexafluorobenzene
IUPAC name: 1,2,3,4,5,6-Hexafluorobenzene
CAS No.: 392-56-3
EINECS: 206-876-2
Molecular Formula: C6F6
Molecular Weight: 186.05 g/mol
Melting Point: 3.7-4.1 °C(lit.)
Density: 1.622 g/cm3
Flash Point: 10 °C
Molar Refractivity: 26.21 cm3
Molar Volume: 114.6 cm3
Boiling Point: 80.5 °C at 760 mmHg
Melting point: 3.7-4.1 °C(lit.)
Enthalpy of Vaporization: 31.66 kJ/mol
Vapour Pressure: 94.5 mmHg at 25°C
Following is the structure of Hexafluorobenzene (CAS NO.392-56-3):
Stability: Stable. Incompatible with strong oxidizing agents. May form complexes with transition metals which can explode when heated. Highly flammable
Product Categories: Fluorobenzene; Fluorous Chemistry; Fluorous Solvents; Synthetic Organic Chemistry; Aryl; C6; Halogenated Hydrocarbons; NMR - Solvents; NMR Solvents and Reagents; C6Stable Isotopes; Alphabetical Listings; G-HStable Isotopes; NMR
The chemical synonymous of Hexafluorobenzene (CAS NO.392-56-3) are 1,2,3,4,5,6-Hexafluorobenzene ; 1,2,3,4,5,6-Hexafluoro-benzene ; Benzene,hexafluoro- ; Hexafluoro-benzen ; Perfluorobenzene
Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| guinea pig | LCLo | inhalation | 11800ppm/4H (11800ppm) | SENSE ORGANS AND SPECIAL SENSES: LACRIMATION: EYE BEHAVIORAL: ATAXIA LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES | National Technical Information Service. Vol. OTS0571186, |
| mouse | LC50 | inhalation | 95gm/m3/2H (95000mg/m3) | LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES | Izvestiya Sibirskogo Otdeleniya Akademii Nauk SSSR, Seriya Biologomeditsinskikh Nauk. Vol. 3, Pg. 91, 1965. |
| rat | LD | oral | > 25gm/kg (25000mg/kg) | BEHAVIORAL: EXCITEMENT GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA" | National Technical Information Service. Vol. OTS0571186, |
Consensus Reports
Reported in EPA TSCA Inventory.
Safety Profile
Mildly toxic by inhalation. Dangerous fire hazard when exposed to heat, flame, or oxidizers. Forms extremely heat-sensitive explosive complexes with metals (e.g., chromium, vanadium, and other transition metals). When heated to decomposition it emits toxic fumes of F−. See also Fluorides.
Hazard Note: Highly Flammable
Hazard Codes: 
Xi, 
F
Risk Statements:
R11 Highly flammable.
R36/37/38 Irritating to eyes, respiratory system and skin.
Safety Statements:
S16 Keep away from sources of ignition - No smoking.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S33 Take precautionary measures against static discharges.
S37/39 Wear suitable gloves and eye/face protection.
Attention:
1. Storage: Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container.
2. Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Avoid ingestion and inhalation.Use spark-proof tools and explosion proof equipment.