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CAS No.: | 3970-21-6 |
---|---|
Name: | 2-Methoxyethoxymethyl chloride |
Article Data: | 9 |
Molecular Structure: | |
Formula: | C4H9ClO2 |
Molecular Weight: | 124.567 |
Synonyms: | 1-(Chloromethoxy)-2-methoxyethane;2,5-Dioxahexyl chloride;2-(Chloromethoxy)ethoxymethane;Chloromethyl 2-methoxyethyl ether;Methoxyethoxymethyl chloride;b-Methoxyethoxymethyl chloride;MEM chloride; |
EINECS: | 223-589-8 |
Density: | 1.049 g/cm3 |
Melting Point: | 200-202 °C |
Boiling Point: | 161.3 °C at 760 mmHg |
Flash Point: | 32.4 °C |
Solubility: | It hydrolyzes with water. |
Appearance: | Clear colourless liquid |
Hazard Symbols: | T |
Risk Codes: | 45-10-36/37/38-20/21/22-46-40-23/24/25 |
Safety: | 53-26-36/37/39-45-16-23 |
Transport Information: | UN 2810 6.1/PG 2 |
PSA: | 18.46000 |
LogP: | 0.84570 |
Conditions | Yield |
---|---|
With hydrogenchloride | 87% |
With hydrogenchloride In water | 48% |
With hydrogenchloride at 15 - 20℃; for 3.25h; | |
With hydrogenchloride In dichloromethane at -10℃; for 0.0333333h; |
thionyl chloride
bis(dimethoxyethyoxyl)methane
2-Methoxyethoxymethyl chloride
Conditions | Yield |
---|---|
With sulfur dioxide | 70% |
Conditions | Yield |
---|---|
With hydrogenchloride |
A
2-Methoxyethoxymethyl chloride
B
(methoxyethoxy)methyl chloromethyl ether
Conditions | Yield |
---|---|
With hydrogenchloride |
2-Methoxyethoxymethyl chloride
(3aR,4S,7S,7aR)-7-Hydroxy-4-(toluene-4-sulfonyl)-3a,4,7,7a-tetrahydro-benzo[1,3]dioxole-4-carboxylic acid methyl ester
(3aR,4S,7S,7aR)-7-(2-Methoxy-ethoxymethoxy)-4-(toluene-4-sulfonyl)-3a,4,7,7a-tetrahydro-benzo[1,3]dioxole-4-carboxylic acid methyl ester
Conditions | Yield |
---|---|
With N-ethyl-N,N-diisopropylamine In chloroform 1.) 0 deg C, 15 min; 2.) reflux, 13 h; | 100% |
2-Methoxyethoxymethyl chloride
(7R,10R)-10-Methyl-1,4-dioxa-spiro[4.5]decan-7-ol
(3R,6R)-6-methyl-3-<(2-methoxyethoxy)methoxy>-1-(1,3-dioxolan-2-yl)cyclohexanone
Conditions | Yield |
---|---|
With sodium hydride In N,N-dimethyl-formamide at 0℃; for 2h; | 100% |
2-Methoxyethoxymethyl chloride
L-693,549
Conditions | Yield |
---|---|
With N-ethyl-N,N-diisopropylamine In dichloromethane for 24h; Ambient temperature; | 100% |
2-Methoxyethoxymethyl chloride
Conditions | Yield |
---|---|
With N-ethyl-N,N-diisopropylamine In dichloromethane for 24h; Ambient temperature; | 100% |
2-Methoxyethoxymethyl chloride
4-Hydroxyacetophenone
1-(4-((2-methoxyethoxy)methoxy)phenyl)ethanone
Conditions | Yield |
---|---|
With N-ethyl-N,N-diisopropylamine In dichloromethane for 4h; | 100% |
With potassium carbonate In acetone for 1h; Heating; |
2-Methoxyethoxymethyl chloride
benzyl alcohol
<<(methoxyethoxy)methoxy>methyl>benzene
Conditions | Yield |
---|---|
100% | |
With N-ethyl-N,N-diisopropylamine |
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Molecular Structure of 2-Methoxyethoxymethyl chloride(3970-21-6):
IUPAC Name:1-(chloromethoxy)-2-methoxyethane
Molecular Formula:C4H9ClO2
Molecular Weight:124.566060 g/mol
Appearance:colorless clear liquid
Density:1.049 g/cm3
Flash Point:32.4 °C
Enthalpy of Vaporization:38.15 kJ/mol
Boiling Point:161.3 °C at 760 mmHg
Vapour Pressure:2.99 mmHg at 25 °C
Water Solubility:8.806e+004 mg/L at 25 °C
Refractive index:n20/D 1.427(lit.)
Sensitive:Moisture
EINECS:223-589-8
Synonyms of 2-Methoxyethoxymethyl chloride(3970-21-6):
1-(chloromethoxy)-2-methoxy-ethan;1-Chloro-2,5-dioxahexane;2-Methoxy-1-(Chloromethoxy);Ethane, 1-(chloromethoxy)-2-methoxy-;BETA-METHOXYETHOXYMETHYL CHLORIDE;ETHYLENE GLYCOL CHLOROMETHYL METHYL ETHER;MEM CHLORIDE;ALKOXYETHOXYMETHYLCHLORIDE
Categories of 2-Methoxyethoxymethyl chloride(3970-21-6):
Protection & Derivatization Reagents (for Synthesis);Synthetic Organic Chemistry
First Aid Measures of 2-Methoxyethoxymethyl chloride(3970-21-6):
Eyes:Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:Get medical aid. Wash mouth out with water.
Inhalation:Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Storage of 2-Methoxyethoxymethyl chloride(3970-21-6):
Keep away from sources of ignition. Store in a tightly closed container. Keep under a nitrogen blanket. Refrigerator/flammables.