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| CAS No.: | 4016-11-9 |
|---|---|
| Name: | ETHYL GLYCIDYL ETHER |
| Article Data: | 20 |
| Molecular Structure: | |
|
|
|
| Formula: | C5H10O2 |
| Molecular Weight: | 102.133 |
| Synonyms: | 1,2-Epoxy-3-ethoxypropane;2-(Ethoxymethyl)oxirane;Oxirane, (ethoxymethyl)-;Ethyl glycidyl ether;1-Ethoxy-2,3-epoxypropane; |
| Density: | 0.975g/cm3 |
| Boiling Point: | 130.3°Cat760mmHg |
| Flash Point: | 23.5°C |
| Hazard Symbols: |
 Xi
|
| Risk Codes: | R36/37/38; R10 |
| Safety: | Mutation data reported. A flammable liquid. When heated to decomposition it emits acrid smoke and irritating vapors. |
| PSA: | 21.76000 |
| LogP: | 0.42170 |
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Chemistry
IUPAC Name: 2-(Ethoxymethyl)oxirane
Synonyms of Ethyl glycidyl ether (CAS NO.4016-11-9): (Ethoxymethyl)oxirane ; 1,2-Epoxy-3-ethoxypropane ; 3-Ethoxy-1,2-epoxypropane ; Ethyl glycidyl ether ; Oxirane, (ethoxymethyl)- ; Propane, 1,2-epoxy-3-ethoxy- ; Propane, 1,2-epoxy-3-ethoxy-
Product Categories: Oxiranes;Simple 3-Membered Ring Compounds
InChI: InChI=1/C5H10O2/c1-2-6-3-5-4-7-5/h5H,2-4H2,1H3
CAS NO: 4016-11-9
Molecular Formula: C5H10O2
Molecular Weight : 102.1317
Molecular Structure: 
EINECS: 223-671-3
H bond acceptors: 2
H bond donors: 0
Freely Rotating Bonds: 3
Polar Surface Area: 21.76 Å2
Index of Refraction: 1.42
Molar Refractivity: 26.53 cm3
Molar Volume: 104.7 cm3
Surface Tension: 31.5 dyne/cm
Density: 0.975 g/cm3
Flash Point: 23.5 °C
Enthalpy of Vaporization: 35.28 kJ/mol
Boiling Point: 130.3 °C at 760 mmHg
Vapour Pressure: 11.9 mmHg at 25°C
Storage temp: Flammables area
Appearance: clear colorless liquid.
Toxicity Data With Reference
| 1. | mmo-sat 8 mmol/L | CBINA8 Chemico-Biological Interactions. 45 (1983),153. | ||
| 2. | mmo-klp 500 µmol/L | MUREAV Mutation Research. 89 (1981),269. |
Consensus Reports
Reported in EPA TSCA Inventory.
Safety Profile
Hazard Codes: 
Xi
Risk Statements: 36/37/38-10
R10: Flammable.
R36/37/38: Ethyl glycidyl ether (CAS NO.4016-11-9) is irritating to eyes, respiratory system and skin.
Safety Statements: 37/39-26-16
S16: Keep away from sources of ignition.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S37/39: Wear suitable gloves and eye/face protection.
RIDADR: 2752
RTECS: TZ3200000
HazardClass: 3.2
PackingGroup: III
Mutation data reported. A flammable liquid. When heated to decomposition it emits acrid smoke and irritating vapors.
Standards and Recommendations
DOT Classification: 3; Label: Flammable Liquid
Specification
1.Air & Water Reactions :Highly flammable. Soluble with possible partial decomposition in water.
2.Reactivity Profile: An epoxide and ether. Ethers can act as bases. They form salts with strong acids and addition complexes with Lewis acids. The complex between diethyl ether and boron trifluoride is an example. Ethers may react violently with strong oxidizing agents. In other reactions, which typically involve the breaking of the carbon-oxygen bond, ethers are relatively inert. Epoxides are highly reactive. They polymerize in the presence of catalysts or when heated. These polymerization reactions can be violent. Compounds in this group react with acids, bases, and oxidizing and reducing agents. They react, possibly violently with water in the presence of acid and other catalysts.
3.Health Hazard: Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control may cause pollution.
4.Fire Hazard :HIGHLY FLAMMABLE: Ethyl glycidyl ether (CAS NO.4016-11-9) will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.