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407-97-6

Basic Information
CAS No.: 407-97-6
Name: 1-Bromo-5-fluoropentane
Article Data: 3
Molecular Structure:
Molecular Structure of 407-97-6 (1-Bromo-5-fluoropentane)
Formula: C5H10BrF
Molecular Weight: 169.037
Synonyms: 1-Bromo-5-fluoropentane;5-Fluoroamyl bromide;
Density: 1.303 g/cm3
Boiling Point: 162 °C at 760 mmHg
Flash Point: 50.1 °C
Solubility: Soluble in methanol (in methanol). Slightly soluble in water.
PSA: 0.00000
LogP: 2.52110
Synthetic route
34626-51-2

5-bromopentan-1-ol

407-97-6

1-bromo-5-fluoropentane

Conditions
ConditionsYield
With diethylamino-sulfur trifluoride In dichloromethane at -70 - 20℃; Inert atmosphere;61%
111-24-0

1,5-dibromo-pentane

407-97-6

1-bromo-5-fluoropentane

Conditions
ConditionsYield
With potassium fluoride; diethylene glycol at 100℃;
120-72-9

indole

407-97-6

1-bromo-5-fluoropentane

407-25-0

trifluoroacetic anhydride

C15H15F4NO

Conditions
ConditionsYield
Stage #1: indole With sodium hydride In N,N-dimethyl-formamide at 0℃; for 0.166667h;
Stage #2: 1-bromo-5-fluoropentane In N,N-dimethyl-formamide for 1h;
Stage #3: trifluoroacetic anhydride In N,N-dimethyl-formamide for 1h;
95%
Stage #1: indole With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0℃; for 0.166667h; Inert atmosphere;
Stage #2: 1-bromo-5-fluoropentane In N,N-dimethyl-formamide; mineral oil at 0 - 20℃; for 1h; Inert atmosphere;
Stage #3: trifluoroacetic anhydride In N,N-dimethyl-formamide; mineral oil at 0 - 20℃; for 1h; Inert atmosphere;
Stage #1: indole With sodium hydride In N,N-dimethyl-formamide at 0 - 20℃; for 0.5h; Inert atmosphere;
Stage #2: 1-bromo-5-fluoropentane In N,N-dimethyl-formamide at 0 - 20℃; for 1h; Inert atmosphere;
Stage #3: trifluoroacetic anhydride In N,N-dimethyl-formamide at 0 - 20℃; for 2h; Inert atmosphere;
407-97-6

1-bromo-5-fluoropentane

118-55-8

phenyl Salicylate

6-fluoro-1-(2-hydroxyphenyl)hexan-1-one

Conditions
ConditionsYield
With 1,10-Phenanthroline; nickel(II) bromide diethylene glycol dimethyl ether; zinc In N,N-dimethyl-formamide at 60℃; for 10h; Inert atmosphere; Sealed tube;83%
407-97-6

1-bromo-5-fluoropentane

69843-08-9

1-(1,1,1-trifluoroprop-2-en-2-yl)-4-methoxybenzene

1-methoxy-4-(1,1,8-trifluorooct-1-en-2-yl)benzene

Conditions
ConditionsYield
With 3,4,7,8-Tetramethyl-o-phenanthrolin; (η(5)-indenyl)trichlorotitanium; nickel dibromide; zinc In N,N-dimethyl acetamide at 60℃; for 24h; Schlenk technique; Inert atmosphere;82%
407-97-6

1-bromo-5-fluoropentane

119072-55-8, 7188-38-7

tert-butylisonitrile

N-(tert-butyl)-6-fluorohexanamide

Conditions
ConditionsYield
With 1,3-bis[(diphenylphosphino)propane]dichloronickel(II); water; sodium t-butanolate In acetonitrile at 40℃; for 22h; Inert atmosphere; Sealed tube;78%

N-cyclopropyl-1-{4-[(ethylamino)carbonyl]-2-hydroxyphenyl}-5-methyl-1H-1,2,3-triazole-4-carboxamide

407-97-6

1-bromo-5-fluoropentane

N-cyclopropyl-1-{4-[(ethylamino)carbonyl]-2-[(5-fluoropentyl)oxy]phenyl}-5-methyl-1H-1,2,3-triazole-4-carboxamide

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 50℃;77%
407-97-6

1-bromo-5-fluoropentane

476414-52-5, 607706-85-4

N-[(1Z)-8-mercapto-5,6-dimethyl-3-oxo-2,3-dihydro-1H-imidazo[5,1-c][1,4]thiazin-1-ylidene]-4-methylbenzenesulfonamide

476420-58-3, 607706-88-7

N-{(1Z)-8-[(5-fluoropentyl)thio]-5,6-dimethyl-3-oxo-2,3-dihydro-1H-imidazo[5,1-c][1,4]thiazin-1-ylidene}-4-methylbenzenesulfonamide

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide Heating;77%
407-97-6

1-bromo-5-fluoropentane

103-67-3

benzyl-methyl-amine

N-benzyl-5-fluoro-N-methylpentan-1-amine

Conditions
ConditionsYield
With potassium carbonate In acetonitrile at 60℃; for 48h;76%
407-97-6

1-bromo-5-fluoropentane

629-05-0

n-octyne

1-fluorotridec-6-yne

Conditions
ConditionsYield
With methyllithium In tetrahydrofuran at 0 - 20℃; for 1.5h; Inert atmosphere;73%
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Specification

The Pentane,1-bromo-5-fluoro- is an organic compound with the formula C5H10BrF. The IUPAC name of this chemical is 1-bromo-5-fluoropentane. With the CAS registry number 407-97-6, it is also named as 5-Fluoroamyl bromide.

Physical properties about Pentane,1-bromo-5-fluoro- are: (1)ACD/LogP: 2.50; (2)ACD/LogD (pH 5.5): 2.5; (3)ACD/LogD (pH 7.4): 2.5; (4)ACD/BCF (pH 5.5): 46.5; (5)ACD/BCF (pH 7.4): 46.5; (6)ACD/KOC (pH 5.5): 543.47; (7)ACD/KOC (pH 7.4): 543.47; (8)#Freely Rotating Bonds: 4; (9)Index of Refraction: 1.424; (10)Molar Refractivity: 33.1 cm3; (11)Molar Volume: 129.6 cm3; (12)Polarizability: 13.12×10-24cm3; (13)Surface Tension: 25.9 dyne/cm; (14)Density: 1.303 g/cm3; (15)Flash Point: 50.1 °C; (16)Enthalpy of Vaporization: 38.22 kJ/mol; (17)Boiling Point: 162 °C at 760 mmHg; (18)Vapour Pressure: 2.89 mmHg at 25°C.

You can still convert the following datas into molecular structure:
(1)SMILES: BrCCCCCF
(2)InChI: InChI=1/C5H10BrF/c6-4-2-1-3-5-7/h1-5H2
(3)InChIKey: GMYIZICPHREVDH-UHFFFAOYAM
(4)Std. InChI: InChI=1S/C5H10BrF/c6-4-2-1-3-5-7/h1-5H2
(5)Std. InChIKey: GMYIZICPHREVDH-UHFFFAOYSA-N

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intraperitoneal 10480ug/kg (10.48mg/kg)   Canadian Journal of Biochemistry and Physiology. Vol. 36, Pg. 339, 1958.