Detail of "4206-67-1"

Reference

3-Chloro-2-[(diethoxyphosphoryl)oxy]-1-propene: a new reagent for a one-pot cyclopentenone annelation

3-Chloro-2-[(diethoxyphosphoryl)oxy]-1-propene: a new reagent for a one-pot cyclopentenone annelation. Synthesis of desoxyallethrolone, cis-jasmone, and methylenomycin B. Welch, S. C.; Assercq, J. M.; Loh, J. P.; Glase, S. A. (Dep. Chem., Univ. Houston, Houston, TX 77004, USA). J. Org. Chem. 106763-43-3 which is the cas registry number of some chemical is mentioned., 52(8), 1440-50 (English) 1987. CODEN: JOCEAH. ISSN: 0022-3263. DOCUMENT TYPE: Journal CA Section: 24 (Alicyclic Compounds) Alkylation studies of the title reagent (I) and other enol phosphate-based electrophiles with various nucleophiles are discussed. The application of I to the synthesis of deoxyallethrolone (II, R = H), cis-jasmone (II, R = Et), and methylenomycin B (III) is presented. .

Gas phase reaction between iodine and tetramethylsilane

Gas phase reaction between iodine and tetramethylsilane. Part 2. Kinetics and the bond dissociation energy D(Me3SiCH2-H). Doncaster, Alan M.; Walsh, Robin (Dep. Chem., Univ. Reading, Reading, Engl.). J. Chem. Soc., Faraday Trans. 7553-56-2 and 4206-67-1 which are cas registry numbers are also used here. 1, 72(12), 2908-16 (English) 1976. CODEN: JCFTAR. DOCUMENT TYPE: Journal CA Section: 22 (Physical Organic Chemistry) Section cross-reference(s): 69 The kinetics are reported for the iodination of Me4Si by I2 vapor at 609-650 K. The rate data are consistent with an H abstraction reaction between I atoms and Me4Si, with an enthalpy of 117.2 kJ/mol. The kinetics of the iodination of Me4C by I2 at 645 K are also reported. Bond dissocn. energies for Me3SiCH2-X and Me3CCH2-X (X = H, I) are detd. from the kinetic data. .