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42422-68-4

Basic Information
CAS No.: 42422-68-4
Name: BETA-ZEARALANOL
Article Data: 5
Molecular Structure:
Molecular Structure of 42422-68-4 (BETA-ZEARALANOL)
Formula: C18H26O5
Molecular Weight: 322.401
Synonyms: |A-Zearanol;Taleranol;(3S,7S)-3,4,5,6,7,8,9;|A-Zearalanol;Taleranolum;|A-Zeranol;
Density: 1.153g/cm3
Melting Point: 134-137oC
Boiling Point: 576°Cat760mmHg
Flash Point: 207.9°C
Hazard Symbols: 4844761
Risk Codes: R60; R36/37/38
Safety: 4844761
PSA: 86.99000
LogP: 3.29080
Synthetic route
71030-11-0

beta-zearalenol

42422-68-4

taleranol

Conditions
ConditionsYield
With 5 mol% Pd/C; hydrogen In ethanol at 20℃;97%
With hydrogen; palladium on activated charcoal at 20℃; under 750.075 Torr;
17924-92-4

zearalenone

42422-68-4

taleranol

Conditions
ConditionsYield
With dipotassium hydrogenphosphate; sodium chloride In N,N-dimethyl-formamide glucose, yeast extract, neopeptone, Aspergillus niger X-170;50%
Multi-step reaction with 2 steps
1: sodium tetrahydroborate / methanol / 3 h / 0 - 20 °C / Inert atmosphere
2: hydrogen; 5 mol% Pd/C / ethanol / 20 °C
View Scheme
325142-22-1

(3S,7R)-7,14,16-trihydroxy-3-methyl-3,4,5,6,7,8,9,10,11,12-decahydro-1H-2-benzoxacyclotetradecin-1-one

A

42422-68-4

taleranol

B

26538-44-3

zeranol

Conditions
ConditionsYield
With water at 40℃; for 96h; lipases from pseudomonas species; other lipases; Yield given. Yields of byproduct given;
With water at 40℃; for 96h; lipases from pseudomonas species, other lipases; Yield given. Yields of byproduct given;
37786-44-0, 39594-22-4, 39594-23-5

Acetic acid (S)-2,4-dihydroxy-7-methyl-5-oxo-7,8,9,10,11,12,13,14,15,16-decahydro-5H-6-oxa-benzocyclotetradecen-11-yl ester

A

42422-68-4

taleranol

B

26538-44-3

zeranol

Conditions
ConditionsYield
With water at 40℃; for 96h; lipases from pseudomonas fluorescens; other lipases; Yield given. Yields of byproduct given;
With water at 40℃; for 96h; lipases from pseudomonas fluorescens, other lipases; Yield given. Yields of byproduct given;
108-05-4

vinyl acetate

26538-44-3

zeranol

A

42422-68-4

taleranol

B

6'-Acetyl-beta-zearalanol

Conditions
ConditionsYield
With Geotrichum candidum lipase In n-heptan1ol at 30℃; for 48h; Acetylation;
108-05-4

vinyl acetate

26538-44-3

zeranol

A

42422-68-4

taleranol

B

Acetic acid (7S,11R)-2,4-dihydroxy-7-methyl-5-oxo-7,8,9,10,11,12,13,14,15,16-decahydro-5H-6-oxa-benzocyclotetradecen-11-yl ester

Conditions
ConditionsYield
With Candida antarctica B lipase In n-heptan1ol at 30℃; for 48h; Acetylation;
42422-68-4

taleranol

74-88-4

methyl iodide

2,4-dimethoxy-β-zearalanol

Conditions
ConditionsYield
With potassium carbonate In acetone at 20℃; Inert atmosphere;72%

uridine 5'-diphosphoglucuronic acid

42422-68-4

taleranol

A

1032558-35-2

β-zearalanol 6'-O-β-D-glucuronide

B

1032558-33-0

β-zearalanol 4-O-β-D-glucuronide

Conditions
ConditionsYield
With uridine 5'-diphosphoglucuronyl transferase; calcium chloride; D,L-dithiothreitol; bovine serum albumin In dimethyl sulfoxide at 30℃; for 24h; pH=8; aq. buffer; Enzymatic reaction;A 12%
B 62%
42422-68-4

taleranol

74-88-4

methyl iodide

4-methoxy-β-zearalanol

Conditions
ConditionsYield
With potassium carbonate In acetone at 20℃; Inert atmosphere;58%
108-05-4

vinyl acetate

42422-68-4

taleranol

6'-Acetyl-beta-zearalanol

Conditions
ConditionsYield
Pseudomonas fluorescens In n-heptane at 25℃; Rate constant; various solvents;
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