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4342-36-3

Basic Information
CAS No.: 4342-36-3
Name: TRIBUTYLTIN BENZOATE
Article Data: 35
Molecular Structure:
Molecular Structure of 4342-36-3 (TRIBUTYLTIN BENZOATE)
Formula: C19H32 O2 Sn
Molecular Weight: 411.172
Synonyms: Stannane,(benzoyloxy)tributyl- (8CI,9CI); Tin, (benzoyloxy)tributyl- (7CI); Tributyltinbenzoate (6CI); (Benzoyloxy)tributylstannane; (Benzoyloxy)tributyltin; NSC221308; Tri-n-butyltin benzoate; Tributylstannyl benzoate
Density: g/cm3
Melting Point: 16-18°C
Boiling Point: 166-168°C 1mm
Flash Point: °C
Hazard Symbols: A poison by ingestion. TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (skin).
Risk Codes: 21-25-36/38-48/23/25-50/53
Safety: Poison by ingestion and intravenous routes. Moderately toxic by subcutaneous route. See also TIN COMPOUNDS. When heated to decomposition it emits acrid smoke and irritating fumes.

Analytical Methods:

   

For occupational chemical analysis use NIOSH: Organotin Compounds 5504.

PSA: 26.30000
LogP: 6.18920
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    Melting point 16-18°C Boiling point 166-168°C 1mm density 1.193 g/mL at 25 °C(lit.) refractive index n20/D 1.5182(lit.) Fp >230 °F Safety Information Hazard Codes T,N Risk Statements 21-25-36/38-48/23/25-

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Chemistry

IUPAC Name: Tributylstannyl benzoate
Synonyms: (Benzoyloxy)(tributyl)stannan ; (Benzoyloxy)(tributyl)stannane ; Benzoyloxytributylstannane ; Biomet 11 ; Stannane, (benzoyloxy)tributyl- ; Stannane, (benzoyloxy)tributyl-
Product Categories: Organometallic Reagents;Organotin;Organotins
Molecular Formula of Benzoyloxytributylstannane (CAS NO.4342-36-3) : C19H32O2Sn
Molecular Weight of Benzoyloxytributylstannane (CAS NO.4342-36-3) : 411.17
Molecular Structure of Benzoyloxytributylstannane (CAS NO.4342-36-3) : 
CAS NO: 4342-36-3
EINECS: 224-399-8
Mol File: 4342-36-3.mol
Flash Point: 197.7 °C
Enthalpy of Vaporization: 65.46 kJ/mol
Boiling Point: 403.4 °C at 760 mmHg
Vapour Pressure: 1.02E-06 mmHg at 25°C
Melting point: 16-18°C

Toxicity Data With Reference

1.    

orl-rat LD50:132 mg/kg

    ARZNAD    Arzneimittel-Forschung. Drug Research. 19 (1969),934.
2.    

scu-rat LD50:505 mg/kg

    TRIPA7    Tin Research Institute, Publication . (The Institute, Fraser Rd., Greenford UB6 7AQ,Middlesex, England.: ) No. 1-1934-1973,1.
3.    

orl-mus LD50:108 mg/kg

    ATXKA8    Archiv fuer Toxikologie. 23 (1968),283.
4.    

ivn-mus LD50:178 mg/kg

    CSLNX*    U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) NX#00090 .

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Poison by ingestion and intravenous routes. Moderately toxic by subcutaneous route. See also TIN COMPOUNDS. When heated to decomposition it emits acrid smoke and irritating fumes.
Hazard Codes ToxicT,DangerousN
Risk Statements 21-25-36/38-48/23/25-50/53
R21:Harmful in contact with skin. 
R25 :Toxic if swallowed. 
R36/38:Irritating to eyes and skin. 
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 
R48/23/25: Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed
Safety Statements 35-36/37/39-45-60-61
S35:This material and its container must be disposed of in a safe way. 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S60:This material and its container must be disposed of as hazardous waste. 
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
RIDADR UN 2788 6.1/PG 3
WGK Germany 3
RTECS WH6710000
TSCA Yes
HazardClass 6.1(b)
PackingGroup III

Standards and Recommendations

OSHA PEL: TWA 0.1 mg(Sn)/m3 (skin)
ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (skin).
DFG MAK: 0.0021 ppm (0.05 mg/m3)
NIOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn)/m3

Analytical Methods

For occupational chemical analysis use NIOSH: Organotin Compounds 5504.

Specification

Category: Pesticides
Toxicity classification: highly toxic
Acute toxicity: Oral - rat LD50: 132 mg / kg; Oral - Mouse LD50: 108 mg / kg
Flammable hazardous characteristics: flammable; burning of stimulating smoke
Storage features: the Treasury ventilated, low-temperature,drying; kept separate from food raw materials.
Fire-extinguishing agent: dry powder, foam, sand, carbon dioxide, water mist
Professional Standards: TWA 0.1 mg (Sn) / m3; STAL 0.2 mg (Sn) / m3