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Detail of "4414-88-4"

  • CAS Number:
  • 4414-88-4
  • Name:

  • 1H-Benzimidazole-2-acetonitrile

  • Superlist Name:
  • 2-(Cyanomethyl)benzimidazole
  • Molecular Structure:
  • Formula:
  • C9H7 N3
  • Molecular Weight:
  • 157.19
  • Synonyms:
  • 2-Benzimidazoleacetonitrile(6CI,7CI,8CI); (1H-Benzimidazol-2-yl)acetonitrile;(2-Benzimidazolyl)acetonitrile; 1-H-Benzoimidazol-2-yl-acetonitrile;2-(Cyanomethyl)benzimidazol; 2-(Cyanomethyl)benzimidazole;2-(Cyanomethyl)benzoimidazole; 2-Benzimidazolacetonitrile;2-Cyanomethylbenz[d]imidazole; NSC 525203
  • EINECS:
  • 224-574-9
  • Density:
  • 1.295 g/cm3
  • Melting Point:
  • 210-215 ºC
  • Boiling Point:
  • 439.5 ºC at 760 mmHg
  • Flash Point:
  • 142.5 ºC
  • Appearance:
  • yellowish powder
  • Hazard Symbols:
  • Risk Codes:
  • R20/21/22;R36/37/38   
  • Safety:
  • Poison by intravenous route. See also NITRILES. When heated to decomposition it emits toxic fumes of NOx. Details
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CAS No.4414-88-4 2-(Cyanomethyl)benzimidazole

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CAS No.4414-88-4 2-(Cyanomethyl)benzimidazole

(Benzimidazol-2-yl)acetonitrile

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CAS No:4414-88-4 NAME:? 1H-Benzimidazole-2-acetonitrile

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2-(CYANOMETHYL)BENZIMIDAZOLE

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Reference

Synthesis of phthalimid-3-yl and -4-yl aminoethylenes and pyrroloquinolines and a study of the fluorescence properties
Synthesis of phthalimid-3-yl and -4-yl aminoethylenes and pyrroloquinolines and a study of the fluorescence properties.Some chemicals with cas registry numbers like 20579-79-7 and 107070-47-3 are also used. Rangnekar, D. W.; Rajadhyaksha, D. D. (Dep. Chem. Technol., Univ. Bombay, Bombay 400 019, India). Dyes Pigm., 8(1), 1-10 (English) 1987. CODEN: DYPIDX. ISSN: 0143-7208. DOCUMENT TYPE: Journal CA Section: 41 (Dyes, Organic Pigments, Fluorescent Brighteners, and Photographic Sensitizers) 3-Amino- (I) [20579-79-7] and 4-amino-N-phenylphthalimide (II) [20871-03-8] were condensed with di-Et ethoxymethylenemalonate [87-13-8], Et ethoxymethylenecycanoacetate [94-05-3], and Et ethoxymethyleneacetonate [3788-94-1] to obtain 1-N-(1-N-phenylphthalimid-3-yl)amino-2-disubstittued ethylenes and 1-N-(1-N-phenylphthalimid-4-yl)amino-2-disubstituted ethylenes, resp. The aminoethylenes contg. a 2-Et carboxylate substituent were cyclized in Downtherm A to give the corresponding 3-substituted 4-hydroxy-8-N-phenylpyrrolo[3,4-h]quinoline-7,9-diones and 3-substituted 4-hydroxy-7-N-phenylpyrrolo[3,4-g]quinoline-6,8-diones, resp. I and II were also condensed with Et orthoformate [122-51-0] and compds. contg. an active methylene or active Me group such as phenylacetonitrile [140-29-4], 2-methylbenzimidazole [615-15-6], and benzimidazol-2-ylacetonitrile [4414-88-4] to give different aminoethylene derivs. The fluorescent properties of all these products were studied and some of these compds. were applied to polyester fibers as fluorescent dyes. .
Basic azo dyes
Basic azo dyes. Loew, Peter; Koller, Stefan (Ciba-Geigy A.-G., Switz.). Ger. Offen. DE 2618453 11 Nov 1976, 33 pp. (German). (Germany).In this article, certain chemicals are used. Some of their cas registry numbers are 61480-31-7 and 61480-30-6 CODEN: GWXXBX. CLASS: IC: C09B039-00. PRIORITY: CH 75-5526 29 Apr 1975. DOCUMENT TYPE: Patent CA Section: 40 (Dyes, Fluorescent Whitening Agents, and Photosensitizers) Title compds. (I; R = Me, Ph; R1 = H, Me; X = NMe, CMe2, S), fast yellow dyes for acrylic fibers, were prepd. by quaternization of the corresponding dye bases. Thus, the dye base [61480-35-1] prepd. by coupling diazotized 5-amino-3-methyl-1-phenylpyrazole [1131-18-6] with 2-benzimidazolylacetonitrile [4414-88-4] was heated with Me2SO4 and MgO in PhCl to give I (R = Ph, R1 = H, X = NMe) [61480-34-0]. Four other I were similarly prepd. .
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