Detail of > 4421-09-4
- CAS Number:
- 4421-09-4
- Name:
1,3-Benzodioxole-5-carbonitrile
- Superlist Name:
- Piperonylonitrile
- Formula:
- C8H5NO2
- Molecular Structure:

- Synonyms:
- Piperonylonitrile(6CI,7CI,8CI);1-(Benz[d][1,3]dioxol-5-yl)nitrile;1-Cyano-3,4-methylenedioxybenzene;2H-Benzo[d]-1,3-dioxolane-5-carbonitrile;3,4-(Methylenedioxy)benzonitrile;5-Cyano-1,3-benzodioxole;Benzodioxole-5-carbonitrile;NSC 27009;
- Molecular Weight:
- 147.13
- EINECS:
- 224-590-6
- Density:
- 1.34 g/cm3
- Melting Point:
- 91-93 °C(lit.)
- Boiling Point:
- 257.3 °C at 760 mmHg
- Flash Point:
- 115.4 °C
- Appearance:
- white to beige crystalline powder or needles
- Hazard Symbols:
Xn- Risk Codes:
- 20/21
- Safety:
- 36-23Details
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Reference
- Novel conversion of aromatic thioamides and aldehydes into nitriles with elemental sulfur and sodium nitrite in liquid ammonia
- Novel conversion of aromatic thioamides and aldehydes into nitriles with elemental sulfur and sodium nitrite in liquid ammonia.Several reagents such as 4421-09-4 is used here. Sato, Ryu; Itoh, Kaoru; Itoh, Kazumi; Nishina, Hironori; Goto, Takehiko; Saito, Minoru (Fac. Eng., Univ. Iwate, Iwate 020, Japan). Chem. Lett., (11), 1913-16 (English) 1984. CODEN: CMLTAG. ISSN: 0366-7022. DOCUMENT TYPE: Journal CA Section: 25 (Benzene, Its Derivatives, and Condensed Benzenoid Compounds) Various arom. nitriles were obtained in good yields from arom. thioamides, aldehydes, and related compds. with elemental sulfur and NaNO2 in liq. NH3. A new type of Willgerodt-Kindler reaction is suggested in this study. .
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