Detail of "447-61-0"

CAS Number:
447-61-0
Name:
Benzaldehyde,2-(trifluoromethyl)-
Superlist Name:
2-(Trifluoromethyl)benzaldehyde
Molecular Structure:
Formula:
C₈H₅F₃O
Molecular Weight:
174.12
Synonyms:
o-Tolualdehyde,a,a,a-trifluoro-(6CI,8CI);o-(Trifluoromethyl)benzaldehyde;a,a,a-Trifluoro-o-tolualdehyde;2-Trifluoromethylbenzaldehyde;
EINECS:
207-185-9
Density:
1.293 g/cm³
Melting Point:
-40 °C
Boiling Point:
194.3 °C at 760 mmHg
Flash Point:
61.1 °C
Appearance:
clear colorless to slightly yellow liquid
Hazard Symbols:
Xi
Risk Codes:
36/37/38
Safety:
26-36/37/39-37/39-36 Details

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Reference

Involvement of an oxidation-reduction equilibrium in chromium-mediated enantioselective Nozaki-Hiyama reactions: Involvement of an oxidation-reduction equilibrium in chromium-mediated enantioselective Nozaki-Hiyama reactions. Schrekker, Henri S.; Micskei, Karoly; Hajdu, Csongor; Patonay, Tamas; De Bolster, Martin W. G.; Wessjohann, Ludger A. (Leibniz-Institute of Plant Biochemistry, Halle 06120, Germany). Advanced Synthesis & Catalysis, 346(7), 731-736 (English) 2004 Wiley-VCH Verlag GmbH & Co. KGaA. CODEN: ASCAF7. ISSN: 1615-4150. DOCUMENT TYPE: Journal CA Section: 25 (Benzene, Its Derivatives, and Condensed Benzenoid Compounds) Section cross-reference(s): 22 Ligand-induced enantioselective versions of the chromium(II)-mediated Nozaki-Hiyama reaction, giving access to chiral homoallyl alcs., proved to be very difficult to achieve, esp. if any nucleophile other than the parent allylchromium(III) species was applied. The reaction is also frequently accompanied by the formation of oxidn. side products, predominantly allyl ketones, which can be explained by an Oppenauer-Meerwein-Ponndorf-Verley type mechanism (OMPV reaction). The addn. 870-63-3 and 447-61-0 which are cas registry numbers of chemicals are mentioned. of an enantiopure ligand to racemic chromium homoallyl alcoholate intermediates produced enantiomerically enriched homoallyl alcs. with an enantiomeric excess of up to 32%. This observation not only supports that the proposed OMPV oxidn.-redn. equil. plays a crucial role in Nozaki-Hiyama reactions, but also proves its involvement in enantioselective versions. .

Phosphonopyridines and their 1,4-dihydro derivatives as calcium antagonists, and a process for their preparation: Phosphonopyridines and their 1,4-dihydro derivatives as calcium antagonists, and a process for their preparation. Gandolfi, Carmelo A.; Frigerio, Marco; Spinelli, Silvano; Riva, Carlo; Tofanetti, Odoardo; Tognella, Sergio (Boehringer Biochemia Robin S.p.A., Italy). Eur. Pat. Appl. EP 210571 A1 4 Feb 1987, 18 pp. DESIGNATED STATES: R: AT, BE, CH, DE, FR, GB, IT, LI, LU, NL, SE. (European Patent Organization) CODEN: EPXXDW. CLASS: ICM: C07F009-58. ICS: C07F009-65; A61K031-66. APPLICATION: EP 86-110013 21 Jul 1986. PRIORITY: IT 85-21818 1 Aug 1985. DOCUMENT TYPE: Patent CA Section: 29 (Organometallic and Organometalloidal Compounds) Section cross-reference(s): 1, 27 Title compds. I [n = 0 (arom. 7022-45-9 is also in the experiment. ring), 1 (1,4-dihydropyridine ring); R = (un)substituted alkyl; R1, R2 = H, alkyl, Ph, PhCH2; R3 = bicyclic ring (e.g., naphthyl, a-benzofuroxanyl), heterocyclyl, (un)substituted Ph; R4 = Ac, Bz, cyano, NO2, (un)substituted CONH2, CO2H, Ph; R5 = alkyl, Ph, PhCH2; R 1 alkyl when n = 1 and R4 = carboxy ester group] are prepd. as Ca antagonists (no data). A mixt. of phosphonate (Z/E)-II (prepn. given), Me(H2N)C:CHCO2Et, and HCl catalyst in EtOH was refluxed for 3 h under N to give (nitrophenyl)dihydropyridinephosphonate III. .

Detail of "447-61-0"

Benzaldehyde,2-(trifluoromethyl)-

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CAS No.447-61-0 2-(Trifluoromethyl)benzaldehyde

CAS No.447-61-0 2-(Trifluoromethyl)benzaldehyde

CAS No.447-61-0 2-(Trifluoromethyl)benzaldehyde

CAS No.447-61-0 2-(Trifluoromethyl)benzaldehyde

CAS No.447-61-0 2-(Trifluoromethyl)benzaldehyde

CAS No.447-61-0 2-(Trifluoromethyl)benzaldehyde

CAS No.447-61-0 2-(Trifluoromethyl)benzaldehyde

CAS No.447-61-0 2-(Trifluoromethyl)benzaldehyde

CAS No.447-61-0 2-(Trifluoromethyl)benzaldehyde

CAS No.447-61-0 2-(Trifluoromethyl)benzaldehyde

CAS No.447-61-0 2-(Trifluoromethyl)benzaldehyde

CAS No.447-61-0 2-(Trifluoromethyl)benzaldehyde

CAS No.447-61-0 2-(Trifluoromethyl)benzaldehyde

CAS No.447-61-0 2-(Trifluoromethyl)benzaldehyde

CAS No.447-61-0 2-(Trifluoromethyl)benzaldehyde

CAS No.447-61-0 2-(Trifluoromethyl)benzaldehyde

CAS No.447-61-0 2-(Trifluoromethyl)benzaldehyde

CAS No.447-61-0 2-(Trifluoromethyl)benzaldehyde

CAS No.447-61-0 2-(Trifluoromethyl)benzaldehyde

CAS No.447-61-0 2-(Trifluoromethyl)benzaldehyde

CAS No.447-61-0 2-(Trifluoromethyl)benzaldehyde

CAS No.447-61-0 2-(Trifluoromethyl)benzaldehyde

CAS No.447-61-0 2-(Trifluoromethyl)benzaldehyde

CAS No.447-61-0 2-(Trifluoromethyl)benzaldehyde

CAS No.447-61-0 2-(Trifluoromethyl)benzaldehyde

CAS No.447-61-0 2-(Trifluoromethyl)benzaldehyde

CAS No.447-61-0 2-(Trifluoromethyl)benzaldehyde

CAS No.447-61-0 2-(Trifluoromethyl)benzaldehyde

CAS No.447-61-0 2-(Trifluoromethyl)benzaldehyde

CAS No.447-61-0 2-(Trifluoromethyl)benzaldehyde

Reference