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| CAS No.: | 4530-20-5 |
|---|---|
| Name: | Boc-Glycine |
| Article Data: | 113 |
| Molecular Structure: | |
|
|
|
| Formula: | C7H13NO4 |
| Molecular Weight: | 175.185 |
| Synonyms: | Boc-Gly-OH;tert-Butoxycarbonylglycine;2-(tert-butoxycarbonylamino)acetate;Nalpha-tert-Butyloxycarbonylglycine;t-Butoxycarbonylglycine;N-(Carbo-tert-butoxy)glycine;Glycine, N-[ (1, 1-dimethylethoxy)carbonyl]-;tert-Butyloxycarbonylglycine;N-t-Butyloxycarbonyl glycine;N-[(1, 1-Dimethylethoxy)carbonyl]glycine;N(a)-tert-Butyloxycarbonylglycine;2-(tert-butoxycarbonylamino)acetic acid;N-(tert-butoxycarbonyl)glycine;Glycine, N-carboxy-, N-tert-butyl ester;Glycine, N-carboxy-, N-tert-butyl ester (8CI);N-((1,1-Dimethylethoxy)carbonyl)glycine;N-tert-Butyloxycarbonylglycine;N-t-BOC-Glycine;[(tert-butoxycarbonyl)amino]acetic acid;N-Boc-glycine; |
| EINECS: | 224-864-5 |
| Density: | 1.159 g/cm3 |
| Melting Point: | 86-89 °C(lit.) |
| Boiling Point: | 315.9 °C at 760 mmHg |
| Flash Point: | 144.9 °C |
| Solubility: | Soluble in water |
| Appearance: | white to off-white powder |
| Hazard Symbols: |
 Xn,  Xi
|
| Risk Codes: | 22-41-36/37/38-20/21/22 |
| Safety: | 26-36/37/39-39-36 |
| Transport Information: | UN 2811 6.1/PG 3 |
| PSA: | 75.63000 |
| LogP: | 0.98660 |
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| Conditions | Yield |
|---|---|
| With potassium hydroxide In 1,4-dioxane; water at 20℃; for 12h; | 100% |
| Stage #1: glycine With sodium hydroxide In 1,4-dioxane; water at 0℃; for 0.25h; Stage #2: di-tert-butyl dicarbonate In 1,4-dioxane; water at 0 - 20℃; | 100% |
| With sodium hydroxide In 1,4-dioxane | 100% |
- 83316-95-4
2-oxo-2-phenylethyl 2-(tert-butoxycarbonylamino)acetate
A
- 4530-20-5
BOC-glycine
B
- 98-86-2
acetophenone
| Conditions | Yield |
|---|---|
| With N,N,N',N'-tetramethyl-o-phenylenediamine In acetonitrile for 2h; Irradiation; | A 100% B n/a |
| Conditions | Yield |
|---|---|
| With hydrogen; palladium on activated charcoal for 3h; | A 100% B n/a |
A
- 4530-20-5
BOC-glycine
B
- 1033736-87-6
C16H10O3S
| Conditions | Yield |
|---|---|
| In chloroform-d1 for 0.25h; Solvent; Photolysis; Inert atmosphere; | A 97% B n/a |
| Conditions | Yield |
|---|---|
| With sodium hydroxide In 1,4-dioxane at 20℃; for 8h; | 95% |
| Conditions | Yield |
|---|---|
| With sodium hydroxide In water; acetone at 25℃; for 12h; | 94% |
- 64205-15-8
(N-hydroxy-5-norbornene-2,3-diformylimino)tert-butyl ester
- 56-40-6
glycine
- 4530-20-5
BOC-glycine
| Conditions | Yield |
|---|---|
| With tertiary amine In 1,4-dioxane; water for 3h; | 85% |
| Conditions | Yield |
|---|---|
| With triethylamine In methanol at 20℃; for 0.5h; | 85% |
- 79113-14-7
4-nitrobenzyl N-(tert-butoxycarbonyl)glycinate
- 4530-20-5
BOC-glycine
| Conditions | Yield |
|---|---|
| With sodium dithionite; sodium carbonate In acetonitrile | 80% |
| Conditions | Yield |
|---|---|
| With triethylamine In 1,4-dioxane; water for 0.166667h; Ambient temperature; | 80% |
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Chemistry
Molecular structure of Boc-glycine (CAS NO.4530-20-5) is:
Product Name: Boc-glycine
CAS Registry Number: 4530-20-5
IUPAC Name: 2-[(2-methylpropan-2-yl)oxycarbonylamino]acetic acid
Molecular Weight: 175.18242 [g/mol]
Molecular Formula: C7H13NO4
XLogP3-AA: 0.5
H-Bond Donor: 2
H-Bond Acceptor: 4
EINECS: 224-864-5
Melting Point: 86-89 °C(lit.)
Water Solubility: soluble
Surface Tension: 40.1 dyne/cm
Density: 1.159 g/cm3
Flash Point: 144.9 °C
Enthalpy of Vaporization: 61.27 kJ/mol
Boiling Point: 315.9 °C at 760 mmHg
Vapour Pressure: 9.08E-05 mmHg at 25°C
Product Categories: Protected Amino Acids;Aminoacids Derivatives;Amino Acid Derivatives;Protected Amino Acid & Peptides;Amino Acids;Glycine [Gly, G];Boc-Amino Acids and Derivative;Amino Acids 13C, 2H, 15N;Absolute Configuration Determination (Exciton Chirality CD Method);Amino Acids (N-Protected);Analytical Chemistry;Biochemistry;Boc-Amino Acids;Enantiomer Excess & Absolute Configuration Determination;Exciton Chirality CD Methodfor (for Monofunctional Compounds);Boc-Amino acid series;Amino Acids & Derivatives
Safety Profile
Safty information about Boc-glycine (CAS NO.4530-20-5) is:
Hazard Codes: 
Xn,Xi
Risk Statements: 22-41-36/37/38-20/21/22
R22:Harmful if swallowed.
R41:Risk of serious damage to the eyes.
R36/37/38:Irritating to eyes, respiratory system and skin.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed.
Safety Statements: 26-36/37/39-39-36
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S39:Wear eye / face protection.
S36:Wear suitable protective clothing.
RIDADR: UN 2811 6.1/PG 3
WGK Germany: 3
Specification
Boc-glycine , its cas register number is 4530-20-5. It also can be called 2-[(2-Methylpropan-2-yl)oxycarbonylamino]acetic acid ; Glycine, N-[(1,1-dimethylethoxy)carbonyl]- ; N-(tert-Butoxycarbonyl)glycine ; Nalpha-tert-Butyloxycarbonylglycine ; t-Butoxycarbonylglycine ; Glycine, N-carboxy-, N-tert-butyl ester (8CI) .It is a white to off-white powder.
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