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4538-50-5

Basic Information
CAS No.: 4538-50-5
Name: Glycidic acid methyl ester
Article Data: 37
Molecular Structure:
Molecular Structure of 4538-50-5 (Glycidic acid methyl ester)
Formula: C4H6O3
Molecular Weight: 102.09
Synonyms: Racemic methyl glycidate;Glycidic acid methyl ester;Methyl 2-oxiranecarboxylate;Methyl oxirane-2-carboxylate;Oxirane-2-carboxylic acid, methyl ester;
Density: 1.246g/cm3
Boiling Point: 97.4 °C at 760 mmHg
Flash Point: 26.2 °C
PSA: 38.83000
LogP: -0.44180
Synthetic route
292638-85-8

acrylic acid methyl ester

4538-50-5

methyl glycidate

Conditions
ConditionsYield
With Mn-trimethyltriazacyclononane; dihydrogen peroxide; sodium L-ascorbate In water; acetonitrile at 0℃; Epoxidation;97%
With sodium hypochlorite; tetrabutyl-ammonium chloride; sodium hydrogencarbonate In water at 40℃; for 1h; Reagent/catalyst; Green chemistry;82%
With sodium hypochlorite In water at 0 - 70℃; Product distribution / selectivity;80%
80-62-6

methacrylic acid methyl ester

4538-50-5

methyl glycidate

Conditions
ConditionsYield
With sodium hypochlorite; carbon dioxide; sodium carbonate In water at 10℃; for 1h;50%
4538-50-5

methyl glycidate

124-38-9

carbon dioxide

1352430-21-7

4-methoxycarbonyl-2-oxo-1,3-dioxolane

Conditions
ConditionsYield
With trimethylbenzylammonium bromide at 70℃; under 33753.4 - 37503.8 Torr; for 15h; Product distribution / selectivity;100%
With tert-butyl methyl ether; tetrabutylammomium bromide at 40℃; under 15001.5 Torr; for 96h; Product distribution / selectivity;94%
With tetrabutylammomium bromide In tert-butyl methyl ether at 40℃; under 15001.5 Torr; for 96h; Reagent/catalyst; Sealed tube;94%
4538-50-5

methyl glycidate

2393-23-9

4-methoxy-benzylamine

1099828-11-1

2-hydroxy-N-(4-methoxybenzyl)-3-(4-methoxybenzylamino)propionamide

Conditions
ConditionsYield
at 60℃; for 6h; Inert atmosphere;99%
4538-50-5

methyl glycidate

108-95-2

phenol

233770-36-0

(R)-2-Hydroxy-3-phenoxy-propionic acid methyl ester

Conditions
ConditionsYield
With (R,R)-(salen)Co(H2O); 3 A molecular sieve In various solvent(s) at -20℃;98%
chiral Co-complex
4538-50-5

methyl glycidate

57-14-7

1,1-dimethylhydrazine

4-hydroxy-1,1-dimethyl-pyrazolidin-3-one

Conditions
ConditionsYield
In isopropyl alcohol at 20℃; for 3h;95%
4538-50-5

methyl glycidate

18982-54-2

o-bromobenzyl alcohol

1612884-62-4

(2R)-3-(2-bromobenzyloxy)-2-hydroxypropionic acid methyl ester

Conditions
ConditionsYield
In acetonitrile at 4℃; for 24h; enantioselective reaction;94%
230-27-3

7,8-benzoquinoline

4538-50-5

methyl glycidate

methyl 3-(benzo[h]quinolin-10-yl)-2-hydroxypropanoate

Conditions
ConditionsYield
With 1,1,1,3',3',3'-hexafluoro-propanol; palladium diacetate; acetic acid at 25℃; for 24h; Inert atmosphere;92%
4538-50-5

methyl glycidate

82731-79-1

diethyl[(trimethylsilyl)acetylenyl]aluminum

C9H16O3Si

Conditions
ConditionsYield
In toluene at 0℃;90%
4538-50-5

methyl glycidate

292638-85-8

acrylic acid methyl ester

Conditions
ConditionsYield
With sodium iodide; tin(ll) chloride In ethanol for 0.05h; Reflux; Green chemistry;85%
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  • methyl oxirane-2-carboxylate

  • Casno:

    4538-50-5

    methyl oxirane-2-carboxylate

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0

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  • Debye Scientific

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Chemistry

Molecular Structure of Oxiranecarboxylic acid, methyl ester (CAS NO.4538-50-5):

IUPAC Name: methyl oxirane-2-carboxylate 
Empirical Formula: C4H6O3
Molecular Weight: 102.0886
CAS: 4538-50-5
H bond acceptors: 3
H bond donors: 0
Freely Rotating Bonds: 2
Polar Surface Area: 38.83Å2
Index of Refraction: 1.444
Molar Refractivity: 21.77 cm3
Molar Volume: 81.8 cm3
Surface Tension: 38.7 dyne/cm
Density: 1.246 g/cm3
Flash Point: 26.2 °C
Enthalpy of Vaporization: 33.69 kJ/mol
Boiling Point: 97.4 °C at 760 mmHg
Vapour Pressure: 41.7 mmHg at 25°C 
InChI
InChI=1/C4H6O3/c1-6-4(5)3-2-7-3/h3H,2H2,1H3
Smiles
O1[C@@H](C1)C(=O)OC

Specification

  Oxiranecarboxylic acid, methyl ester , with CAS number of 4538-50-5, can be called Racemic methyl glycidate ; Glycidic acid methyl ester ; Methyl 2-oxiranecarboxylate ; Methyl oxirane-2-carboxylate ; Oxirane-2-carboxylic acid, methyl ester .