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Detail of "4648-54-8"

  • MSDS Download
  • CAS Number:
  • 4648-54-8
  • Name:

  • Silane, azidotrimethyl-

  • Superlist Name:
  • Azidotrimethylsilane
  • Molecular Structure:
  • Formula:
  • C3H9N3Si
  • Molecular Weight:
  • 115.21
  • Deleted CAS:
  • 150059-64-6
  • Synonyms:
  • Trimethylazidosilane;Trimethylsilicon azide;Trimethylsilyl azide;
  • EINECS:
  • 225-078-5
  • Density:
  • 0.876 g/mL at 20 °C
  • Melting Point:
  • -95 °C
  • Boiling Point:
  • 95-96 °C
  • Flash Point:
  • 6 °C
  • Solubility:
  • decompose in water
  • Appearance:
  • clear colorless to slightly yellow liquid
  • Hazard Symbols:
  • FlammableF, ToxicT, DangerousN
  • Risk Codes:
  • 11-23/24/25-50/53-29
  • Safety:
  • 16-36/37/39-45-8-57-36/37-29 Details
  • Transport Information:
  • UN 1992 3/PG 2
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CAS No.4648-54-8 AzidotrimethylsilaneCompetitive Product

Supplier:Shenyang Bomei Pharmaceutical New Technology Development Co., Ltd [ China (Mainland)]

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CAS No.4648-54-8 Azidotrimethylsilane

Assay:98℅  Appearance:Inqury  Package:100g,500g,6k...

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CAS No.4648-54-8 Azidotrimethylsilane

chemical formula: C3H9N3Si

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CAS No.4648-54-8 Azidotrimethylsilane

TRIMETHYLSILYL AZIDE

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CAS No.4648-54-8 Azidotrimethylsilane

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CAS No.4648-54-8 Azidotrimethylsilane

Assay:98% min  Appearance:clear colorl...  Transportation:UN1992, Clas...

Molecular Formula: C3H9N3Si Molecular Weight: 115.21 Density: 0.876 Boiling Point: 52-53°C (175 mmHg) Flash Point: 6°C

Supplier:Ring Specialty Chemicals Inc. [ Canada]

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CAS No.4648-54-8 Azidotrimethylsilane

Appearance：Colorless or pale yellow liquid Assay：≥ 95.0% Boiling Point：92-95 °C Density：0.876 g/ml at 20°C Flash Point：74°F

Min. Order:1.0Kilogram

Supplier:Zhejiang Bulk Chemical Co., Ltd. [ China (Mainland)]

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Azidotrimethylsilane

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CAS No.4648-54-8 Azidotrimethylsilane

Trimethylsilyl azide

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Raw material for

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Reference

Trimethylsilyl azide
Trimethylsilyl azide. West, Robert; Zigler, Steven (Univ. Wisconsin, Madison, WI, USA). Chem. Eng. News, 62(24), 4 (English) 1984. CODEN: CENEAR. ISSN: 0009-2347. DOCUMENT TYPE: Journal CA Section: 59 (Air Pollution and Industrial Hygiene) Section cross-reference(s): 50, 67 A violent detonation took place during distn. in prepn. of trimethylsilyl azide [4648-54-8]. Traces of azides from the AlCl3 catalysis may have been carried over to the distn. flask and caused the explosion. Prepn. methods which do not use AlCl3 catalysis are probably safer. Otherwise, elaborate shielding against a possible explosion is recommended.
Synthesis, characterization, and crystal structure of 1,3-dipentafluorophenyl-2,2,2,4,4,4-hexazido-1,3-diaza-2,4-diphospheti dine
Synthesis, characterization, and crystal structure of 1,3-dipentafluorophenyl-2,2,2,4,4,4-hexazido-1,3-diaza-2,4-diphospheti dine. Aubauer, Christoph; Karaghiosoff, Konstatin; Klapotke, Thomas M.; Kramer, Gernot; Schulz, Axel; Weigand, Jan (Dept. of Chemistry, Ludwig-Maximilians Univ., Munich, Germany). Zeitschrift fuer Anorganische und Allgemeine Chemie, 627(11), 2547-2552 (English) 2001 Wiley-VCH Verlag GmbH. CODEN: ZAACAB. ISSN: 0044-2313. DOCUMENT TYPE: Journal CA Section: 29 (Organometallic and Organometalloidal Compounds) Section cross-reference(s): 22, 75 1,3-Dipentafluorophenyl-2,2,2,4,4,4-hexazido-1,3-diaza-2,4-diphosphet idine (1) was synthesized by the reaction of [(C6F5)NPCl3]2 with trimethylsilyl azide in CH2Cl2 and characterized by multinuclear NMR and vibrational spectroscopy. The mol. structure of the compd. was detd. by single-crystal x-ray structure anal. [(C6F5)NP(N3)3]2 crystallizes in the monoclinic space group P21ln with a = 9.6414(2), b = 7.4170(1) and c = 15.9447(4) ?, b = 04.4374(0)°, with 2 formula units per unit cell. The bond situation in [(C6F5)NP(N3)3]2 has been studied on the basis of NBO anal. The antisym. stretching vibrational of the azide groups is discussed. The structural diversity of 1 and 1,3-diphenyl-2,2,2,4,4,4-hexazido-1,3-diaza-2,4-diphosphetidine in soln. and in the solid state depending on the aryl substituent at the nitrogen atom is discussed. Keywords dipentafluorophenyl hexazido diazadiphosphetidine prepn crystal mol structure stretching vibration diphenyl hexazido diaza diphosphetidine safety prepn dipentafluorophenyl hexazido diazadiphosphetidine Index Entries Safety in prepn. of dipentafluorophenyl hexazido diazadiphosphetidine Crystal structure Molecular structure of dipentafluorophenylhexazidodiazadiphosphetidine Natural bond orbital Stretching vibration of dipentafluorophenylhexazidodiazadiphosphetidine and dipentafluorophenylhexazidodiazadiphosphetidine 389868-02-4 prepn., crystal structure, and equil. with monomer of 4648-54-8 reaction with dipentafluorophenyl-2,2,2,4,4,4-hexachloro-1,3-diaza-2,4-diphosph etidine 65649-65-2 reaction with trimethylsilyl azide 389868-04-6 soln. formation and equil. with dimer 327629-75-4 theor. calcn. of donor-acceptor interaction in
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